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  • 1
    ISSN: 1572-8862
    Keywords: metal–metal bonds ; two-dimensional homonuclear J-resolved NMR spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The complex Re2Cl6(P-n-Bu3)2 prepared in situ reacts with CH3CN to form a blue-green solution. Addition of the chelating phosphine bis(diphenylphosphino)methane (dppm) results in the formation of the complex [Re2Cl3(μ-dppm)2(NCCH3)2][Cl] (1) upon heating. The two acetonitrile molecules adopt a trans geometry on the rhenium center with the axially coordinated chlorine. The analogous trans benzonitrile species [Re2Cl3(μ-dppm)2(NCC6H5)2][Cl]·2CH2Cl2 (2) is synthesized under the same reaction conditions. The coupling constants of the AA′BB′ 31P{1H} NMR spectra of the compounds were elucidated from 31P–31P homonuclear J-resolved NMR experiments. Additional characterization methods include 31P{1H} NMR spectroscopy, UV-vis spectroscopy, and X-ray crystallography.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 2095-2103 
    ISSN: 1434-1948
    Keywords: Metal-metal bonds ; Rhenium ; Formamidinate ; UV/Vis spectroscopy ; Electrochemistry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Through a variation in the aryl substituents of the formamidinate ligand, a variety of dirhenium compounds has been synthesized with [XArNC(H)NArX]- where Ar is a substituted C6H5 or C6H4 aryl ring and × is p-MeO (1), H (3), m-MeO (4), p-Cl (5), m-Cl (6), m-CF3 (7), p-CF3 (8), 3,4-Cl2 (9), and 3,5-Cl2 (10a, 10b). UV/Vis and NMR spectroscopy and electrochemical data for 1and 3-10 have been obtained. X-ray crystallographic analysis of Re2Cl2(μ-form)4 with four different diarylformamidinate ligands and one analog with two different interstitial solvents are presented; Re2Cl2[(p-MeOC6H4)NCHN(p-MeOC6H4)]4 (1), Re2Cl2[(m-MeOC6H4)-NCHN(m-MeOC6H4)]4 · 2 CH2Cl2 (4), Re2Cl2[(3,4-Cl2C6H3)NCHN(3,4-Cl2C6H3)]4 · 2 CH2Cl2 (9), Re2Cl2[(3,5-Cl2C6H3)NCHN(3,5-Cl2C6H3)]4 · 4 CH2Cl2 (10a), and Re2Cl2[(3,5-Cl2C6H3)NCHN(3,5-Cl2C6H3)]4 · OC4H8 (10b).
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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