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  • metal halide vapors  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 38 (1992), S. 33-43 
    ISSN: 1573-4889
    Keywords: Pack cementation ; aluminide diffusion coatings ; metal halide vapors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An atmospheric pressure sampling mass spectrometer was used to identify the vapor species generated in a halide-activated, cementation pack. Pack powder mixtures containing a Cr-Al binary masteralloy powder, an NH4Cl activator salt, and either ZrO2 or Y2O3 (or neither) were analyzed at 1000°C. Both equilibrium calculations for the pack and mass spectrometer results indicated that volatile AlClx and CrCly species were generated by the pack powder mixture; in packs containing the reactive element oxide, volatile ZrClz and YClw species were formed by the conversion of their oxide sources.
    Type of Medium: Electronic Resource
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