ISSN:
0887-624X
Keywords:
free radical polymerization: kinetics of, catalytic inhibition in, catalytic chain transfer in
;
cobaloxime
;
methylmethacrylate
;
methacrylamide
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Free radical polymerizations of methyl methacrylate and methacrylamide in DMF solution were found to be catalytically inhibited by the addition of the boron fluoride derivative of cobaloxime to the system. The nature of this inhibition is examined and equations which describe the kinetics of these catalytically inhibited polymerizations are developed. Using these equations estimates of the inhibition constants (Cz) of 7.23 × 102 and 2.27 × 102 were estimated for methacrylamide and methyl methacrylate, respectively.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1992.080300416
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