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  • Photocatalysis  (1)
  • microcontact printing  (1)
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  • 1
    ISSN: 1572-879X
    Schlagwort(e): Photocatalysis ; photocatalytic activity ; PbCrO4 ; PbMoO4 ; PbWO4 ; hydrogen evolution ; oxygen evolution ; aqueous solutions ; ternary lead Group IVB oxides
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The relative photocatalytic activity of a series of lead-IVB group oxides (PbCrO4, PbMoO4, and PbWO4) was studied for hydrogen evolution from aqueous methanol solution and for oxygen evolution from aqueous silver nitrate solution. Among the compounds, only PbMoO4 and platinized PbMoO4 powders acted as photocatalysts for oxygen and hydrogen evolution reactions from aqueous solutions, with an activity for oxygen evolution on PbMoO4 comparable to that observed on TiO2.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of nanoparticle research 1 (1999), S. 43-49 
    ISSN: 1572-896X
    Schlagwort(e): titanium oxide ; tantalum oxide ; dielectric ; thin film ; sol–gel ; microcontact printing
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik , Technik allgemein
    Notizen: Abstract TiO2, Ta2O5, and mixed TiO2/Ta2O5 ultrathin films were grown layer-by-layer using a surface sol–gel deposition technique. The technique allows one to prepare smooth films of mixed composition with ångstrom-level control of thickness. The thickness increases per adsorption/hydrolysis cycle were 4.5, 2.1, and 2.5 Å, respectively, for TiO2, Ta2O5, and mixed TiO2/Ta2O5 (1.6sol;1) films. By combining X-ray diffraction and ellipsometric analysis, it was determined that the as-deposited TiO2 films are less dense than bulk TiO2, and do not adhere persistently to Si/SiO2 or Au/2-mercaptoethanol substrates. These ‘green’ films were annealed at 400°C to produce denser and highly adherent films. Patterning the surface by microcontact printing of siloxane polymer thin films allows one to prepare patterned sol–gel oxide thin films.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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