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  • 1
    Electronic Resource
    Electronic Resource
    Influence of the swelling state of seed polymer particles with monomer on the morphology of micron-sized monodispersed composite polymer particles produced by seeded polymerization utilizing the dynamic swelling method (1997)
    Springer
    Colloid & polymer science 275 (1997), S. 888-892 
    Details
    ISSN: 1435-1536
    Keywords: Key words Morphology ; composite particles ; micron-size ; seeded polymerization ; dynamic swelling method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Micron-sized mono-dispersed polystyrene (PS)/poly(n-butyl methacrylate) (PBMA) composite particles (PS/PBMA=2/1 by weight) having a heterogeneous structure in which many fine PBMA domains dispersed in a PS matrix near the particle surface were produced by seeded polymerization of n-butyl methacrylate (BMA) of which almost all had been absorbed by 1.8 μm-sized monodispersed PS seed particles utilizing the dynamic swelling method. The morphology was varied by changing the PS/BMA ratio and polymerization temperature. It was concluded that the swelling state of 2 μm-sized BMA-swollen PS particles in the seeded polymerization process is one of the important factors to control the morphology of the composite particles.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s003960050162
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Preparation of micron-sized monodispersed highly monomer- “adsorbed” polymer particles having snow-man shape by utilizing the dynamic swelling method with tightly cross- linked seed particles (1998)
    Springer
    Colloid & polymer science 276 (1998), S. 887-892 
    Details
    ISSN: 1435-1536
    Keywords: Key words Dynamic swelling method ; cross-linked polymer particles ; monomer adsorption ; micron-size ; monodisperse ; snow-man shape
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Micron-sized, monodispersed highly styrene-“adsorbed” particles having snow-man shape were prepared by the dynamic swelling method (DSM) with tightly cross-linked polymer seed particles as follows. First, 3.8 μm-sized monodispersed polystyrene (PS)/ poly(divinylbenzene) (PDVB) (PS/PDVB = 1/10 wt. ratio) composite particles produced by seeded polymerization utilizing DSM were dispersed in an ethanol/water (6/4, w/w) solution dissolving styrene monomer, and poly(vinyl alcohol) as a stabilizer. Second, water was subsequently added to the dispersion with a micro-feeder at a rate of 2.88 ml/h at room temperature. The cross-linked seed particles adsorbed a large amount of styrene onto the surfaces and resulted in mono-dispersed highly styrene-“adsorbed” snow-man shape particles having about 10 μm in diameter.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s003960050325
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Production of micron-sized monodispersed polymer particles by seeded polymerization for the dispersion of highly monomer-swollen particles prepared with submicron-sized polymer seed particles utilizing the dynamic swelling method (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 2513-2519 
    Details
    ISSN: 0887-624X
    Keywords: dynamic swelling method ; particle ; monodisperse ; micron-size ; seeded polymerization ; emulsion polymerization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: For the purpose of extending the size range of polymer seed particles used in “dynamic swelling method” (DSM), first it was verified theoretically that the submicron-sized polymer particles produced by emulsion polymerization can also absorb a large amount of monomer by DSM in both equilibrium and kinetic control states. Next, on the basis of the theoretical results, experimentally about 2.6 μm-sized styrene-swollen polystyrene (PS) particles were prepared utilizing DSM in the presence of 0.64 μm-sized monodispersed PS seed particles produced by emulsifier-free emulsion polymerization. Moreover, 2.5 μm-sized monodispersed PS particles were produced by the addition of cupric chloride as a water-soluble inhibitor to depress the by-production of submicron-sized PS particles in the seeded polymerization at 30°C with 2,2′-azobis(4-methoxy-2,4-dimethylvaleronitrile) initiator. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. A Polym. Chem. 36: 2513-2519, 1998
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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