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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 57 (1989), S. 1069-1098 
    ISSN: 1572-9613
    Keywords: Block copolymers ; generating function ; Polya's theorem ; gelation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We determine the statistical properties of block copolymer complexes in solution. These complexes are assumed to have the topological structure of (i) a tree or of (ii) a line-dressed tree. In case the structure is that of a tree, the system is shown to undergo a gelation transition at sufficiently high polymer concentration. However, if the structure is that of a line-dressed tree, this transition is absent. Hence, we show the assumption about the topological structure to be relevant for the statistical properties of the system. We determine the average size of the complexes and calculate the viscosity of the system under the assumption that the complexes geometrically can be treated as porous spheres.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 57 (1989), S. 1099-1122 
    ISSN: 1572-9613
    Keywords: Block copolymers ; generating function method ; Polya's theorem ; gelation ; nonnested structures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We determine the statistical properties of block copolymers in solution. These complexes are assumed to have the topological structure of connected graphs with “nonnested” loops and cycles. The generating function method is used to determine the number of topologically different complexes containing a given number of block copolymers. It is shown that at sufficiently high concentration the system undergoes a transition to a gel phase. Furthermore, the average number of polymers per complex is calculated. Finally, the relative increase in viscosity is found under the assumption that the complexes can be treated as porous spheres.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 22 (1996), S. 297-311 
    ISSN: 0271-2091
    Keywords: large-eddy simulation ; numerical schemes ; mixing layer ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A posteriori tests of large-eddy simulations for the temporal mixing layer are performed using a variety of numerical methods in conjunction with the dynamic mixed subgrid model for the turbulent stress tensor. The results of the large-eddy simulations are compared with filtered direct numerical simulation (DNS) results. Five numerical methods are considered. The cell vertex scheme (A) is a weighted second-order central difference. The transverse weighting is shown to be necessary, since the standard second-order central difference (A′) gives rise to instabilities. By analogy, a new weighted fourth-order central difference (B) is constructed in order to overcome the instability in simulations with the standard fourth-order central method (B′). Furthermore, a spectral scheme (C) is tested. Simulations using these schemes have been performed for the case where the filter width equals the grid size (I) and the case where the filter width equals twice the grid size (II). The filtered DNS results are best approximated in case II for each of the numerical methods A, B and C. The deviations from the filtered DNS data are decomposed into modelling error effects and discretization error effects. In case I the absolute modelling error effects are smaller than in case II owing to the smaller filter width, whereas the discretization error effects are larger, since the flow field contains more small-scale contributions. In case I scheme A is preferred over scheme B, whereas in case II the situation is the reverse. In both cases the spectral scheme C provides the most accurate results but at the expense of a considerably increased computational cost. For the prediction of some quantities the discretization errors are observed to eliminate the modelling errors to some extent and give rise to reduced total errors.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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