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  • 76.60  (1)
  • polaron  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 49 (1989), S. 65-68 
    ISSN: 1432-0630
    Schlagwort(e): 66.30 ; 76.60
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract The relaxation timesT 1,T 1q,T 1D, andT 2 for1H in the tetragonal-A phase of HxWO3 have been measured over the temperature range 190 to 490 K. The1H relaxation behaviour appears to be governed by diffusion over inequivalent jump distances, approximating to a short range planar diffusion and a long range isotropic diffusion. Parameters for the latter motion are estimated asE a = 68 kJ/mol andτ 0=2.5×10−13 s. The powder X-ray diffraction pattern for this phase of HxWO3 has been studied over the temperature range 300–470 K. The tetragonal distortion diminishes with temperature and H0.43 WO3 becomes cubic at about 435 K. Volumetric studies of hydrogen evolution show that decomposition accelerates at approximately this temperature.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity 8 (1995), S. 541-544 
    ISSN: 1572-9605
    Schlagwort(e): High-Tc superconductivity ; thermopower ; polaron
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract Transport measurements distinguish the superconductive phase from the parent antiferromagnetic and the overdoped metallic phases in La2−xSrxCuO4. For small x, holes in the CuO2 sheets form non-adiabatic polarons containing, experimentally, five Cu atoms. Within a polaron, a first-order contraction of the mean Cu-O bond length collapses the Hubbard U and transfers spectral weight from the Hubbard bands to the gap between them. In the superconductive phase above Tc, condensation into a polaron liquid produces an ɛ(k) dispersion curve, and dynamic pseudo Jahn-Teller deformations within the polaron give a Seebeck enhancement with Tmax≈140 K. The polarons order pair-wise into 〈110〉 stripes alternating with parent-phase stripes; below Tc, the stripes are perfectly ordered. In the overdoped phase, the parent phase is squeezed out; the vibronic states become homogeneous.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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