ISSN:
1435-1536
Keywords:
Poly(pentafluorostyrene)
;
excimer emission
;
repulsive Coulombic interactions
;
singlet excimer
;
sandwich conformation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract The steady-state fluorescence emission spectrum of poly(pentafluorostyrene) in dilute fluid solution shows no excimer emission. An atomic level modeling study explains why this polymer cannot form an excimer. Repulsive Coulombic interactions prohibit the attainment of the extensive overlap of the two rings in the classic face-to-face sandwich conformation of a singlet excimer.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00657447
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