ISSN:
1573-1111
Keywords:
Crystal structure
;
single crystal
;
crown ethers
;
free radical
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract (C6Cl5)3 C− K+, C12H24O6 is monoclinic, space groupP21 withZ=2,a=10.491(2),b=18.016(7),c=11.670(6) Å, β=103.11(3)°,V=2148(1) Å3, finalR=0.039 for 2339 observed reflections at room temperature. The overall shape of the perchlorotriphenyl free radical is given by the angles between the mean planes of each ring (around 70°). The K+ ion lies at the centre of the 18-membered macrocyclic ring.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00658858
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