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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 95 (1982), S. 205-221 
    ISSN: 1573-5117
    Keywords: morphometry ; hydrology ; turbidity ; colour ; salinity ; alkalinity ; pH ; conductivity ; speciation ; major ; minor and micro elements ; fulvic acids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper attempts to generalize the major controlling factors and their impacts on the physico-chemical environment in Tjeukemeer in relation to the speciation of algal nutrients. Morphometry, man-made hydrology, climate, chemistry of drainage area and biology of the lake appear to control its physico-chemistry the most. Thus the shallow Tieukemeer is vulnerable to wind and therefore almost always completely mixed and often turbid owing to resuspended sediments. In normal summers the lake is oligohaline, hard, eutrophic and alkaline, and in winter it is hard, eutrophic, alkaline and humus-rich. The implications of these properties on the following physico-chemical components and their relevance for the speciation of algal nutrients are discussed: turbidity, colour, halinity, pH, alkalinity, salinity, conductivity, ionic composition, ionic balance and organic matter. Because of the relationships between the physico-chemical environment on the one hand and the speciation and bio-availability of nutrients on the other hand, special attention is given to the speciation of some major and minor elements as derived from ultra filtration experiments. In this context, the metal binding capacity of the organic matter (mainly fulvic acids) is also considered.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Aquatic ecology 24 (1991), S. 145-151 
    ISSN: 1573-5125
    Keywords: Ultrafiltration ; Size distribution ; speciation ; aluminium ; dissolved organic carbon ; humic substances
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Chemical equilibrium calculations treating humic substances as the simple diprotic phtalic acid, predicted no Al-humus at pH〉6.5 in humic lake water. However, dissolved (〈200 nm) organic carbon (DOC) and dissolved Al appeared to be linearly (r=0.597, P〈0.001) correlated in samples from five different humic surface waters in The Netherlands with a DOC range of 10–36 mg.l−1 and a (mean) pH range of 6.85–8.47. Yet, organic carbon (Corg) and Al did no exhibit similar size distributions between 5 and 200 nm revealed by ultrafiltration. Averaged 25% of the Corg and 〉50% of the Al occurred in the fraction 〈5 nm. Only in this fraction the Corg and Al were linearly correlated (r=0.515, P〈0.001). This result suggests the presence of organic ligands in the DOC pool of humic waters having smaller molecular sizes and higher Al stability constants than the humic substances used to model aquatic Al speciation.
    Type of Medium: Electronic Resource
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