ISSN:
1573-9171
Schlagwort(e):
1,2-borylphosphinoethene
;
alkylthiocyanate
;
6-alkylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-diene
;
structure
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract The reaction of 1,2-borylphosphinoethenes with alkylthiocyanates leads to formation of substances having the structure of 6-alkylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-dienes in the crystal state. The structure of the compounds has been proven by x-ray diffraction analysis of 2,2,3-tributyl-4,4,5-triphenyl-5-methylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-diene. The heterocyclic moiety of the molecule is planar within 0.010(2) Å. The methylthio group lies practically in the plane of the heterocycle.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00864194
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