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  • 1
    Electronic Resource
    Electronic Resource
    Silicon-modified carbohydrate surfactants VI: Synthesis of carbosilane, silane, polysilane and non-permethylated siloxane derivatives; the wetting behaviour of epoxy-modified precursor liquids on non-polar surfacesIn remembrance of Professor Dr Edwin Hengge (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 47-58 
    Details
    ISSN: 0268-2605
    Keywords: surfactants ; carbohydrate ; carbosilane ; silane ; wetting ; surface tension ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of carbohydrate surfactants bearing carbosilane, silane, polysilane and non-permethylated siloxane moieties is described. These surfactants consist of three structural elements: (1) a silicon-containing moiety, (2) a spacer and (3) a carbohydrate unit. Additionally two different types of mixed structures have been synthesized: (a) single-chained carbosilane-siloxane surfactants and (b) double-chained combinations of carbo- silanes, silanes and siloxanes. The wetting behaviour of the key intermediates, the allyl glycidyl derivatives, has been investigated by static surface tension (γlv, σ) and wetting tension (γsv-γsl, α) measurements on a non-polar perfluorinated surface (FEP® plate). The contact angles obtained for these pure liquids are not a linear function of the surface tension but depend on the polarity of the substructures. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 2
    Electronic Resource
    Electronic Resource
    Silicon-modified carbohydrate surfactants IX: dynamic wetting of a perfluorinated solid surface by solutions of a siloxane surfactant above and below the critical micelle concentration (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 843-853 
    Details
    ISSN: 0268-2605
    Keywords: carbohydrate-modified phenylsiloxane ; surfactants ; wetting behaviour ; superspreading ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dynamic wetting behaviour on a perfluorinated, low-energy solid has been investigated for a carbohydrate-modified phenylsiloxane surfactant. The surfactant concentration, the rate of interface generation and the [solid/liquid interface area] : [liquid/vapour interface area] ratio were varied systematically. Dynamic data for the liquid/vapour (γlv) and solid/liquid (γsl) interfacial tension as well as their Lifshitz-van der Waals and donor-acceptor contributions were determined under strictly controlled conditions. Since γsl reacts sensitively to variations of the surfactant concentration and the rate of interface generation, the covering of the liquid/non-polar solid interface is assumed to be a spreading limiting factor. The corresponding γlv values remain constant and close to those obtained under equilibrium conditions. Copyright © 1998 John Wiley & Sons, Ltd.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
  • 3
    Electronic Resource
    Electronic Resource
    Silicon-Modified Carbohydrate Surfactants I: Synthesis of Siloxanyl Moieties Containing Straight-chained Glycosides and Amides (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 10 (1996), S. 421-435 
    Details
    ISSN: 0268-2605
    Keywords: siloxanes ; carbohydrate modified ; surfactants ; saccharide ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New siloxanyl-modified carbohydrate surfactants of the amide and glycoside type have been synthesized by coupling between defined as well as higher-molecular-weight siloxanes and carbohydrate structures via spacers of different lengths and hydrophilic power. Linear and branched monohydrogen di-, tri-, tetra- and penta-siloxanes and polyhydrogen siloxanes as well as mono- and di-saccharide lactone structures have been found to be good starting materials for the synthesis of amides, often in quantitative yield, whereas glycosides had to be prepared in low-yield multistep sequences including protection/deprotection steps. Selected strategies were applied to polysiloxanes yielding quantitatively a broad variety of carbohydrate-modified comb-like structures. The new substances were characterized by means of 13C NMR spectroscopy, GC, capillary GC, GC-MS coupling and elemental analysis.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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