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  • 1
    Electronic Resource
    Electronic Resource
    On the theory of adsorption kinetics of ionic surfactants at fluid interfaces 3. Generalization of the model (1991)
    Springer
    Colloid & polymer science 269 (1991), S. 923-928 
    Details
    ISSN: 1435-1536
    Keywords: Adsorptionkinetics ; theory ; ionicsurfactants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract It was shown that, in the case of adsorbing ions, the Boltzmann equation cannot be applied in its classical form, but has to be modified by considering the flux of adsorbing ions. From the comparison with the adsorption of nonionic surfactants a ratio results which is the measure of deceleration of adsorption kinetics due to the electric double layerr=K(y s)/δ(t). At highr-values the electrostatic deceleration controls the adsorption kinetics process.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00657309
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  • 2
    Electronic Resource
    Electronic Resource
    On the theory of adsorption kinetics of ionic surfactants at fluid interfaces (1985)
    Springer
    Colloid & polymer science 263 (1985), S. 420-423 
    Details
    ISSN: 1435-1536
    Keywords: adsorption kinetics ; ionic surfactants ; electric double layer influence ; theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The kinetic equation to describe the adsorption process of ionic surfactants (derived in part 1) will be solved numerically. The results show the effect of parameters such as ion valencyz, thickness of theDL x −1, and surfactant parametersΓeq,K, andK ads on the adsorption process. The results can be used to decide whether the model can explain experimental data on charged surfactant molecules or not.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01410392
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    On the theory of adsorption kinetics of ionic surfactants at fluid interfaces (1983)
    Springer
    Colloid & polymer science 261 (1983), S. 335-339 
    Details
    ISSN: 1435-1536
    Keywords: Adsorption kinetics ; ionic surfactants ; influence of the electric double layer ; theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of the electric field caused by an electric double layer (DL) on the adsorption kinetics of charged surfactant molecules at fluid interfaces is described for the case of high surface potentials and a quasi-equilibrium state of the DL. Known relations for the description of the transport of molecules in the diffusion layer and the DL respectively are used.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01413940
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Adsorption kinetics of surfactants from micellar solutions (1981)
    Springer
    Colloid & polymer science 259 (1981), S. 1124-1128 
    Details
    ISSN: 1435-1536
    Keywords: Adsorption kinetics ; surfactants ; micellar solutions ; theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Es wird ein Modell für die diffusionskontrollierte Adsorption von Tensiden aus mizellaren Lösungen angegeben und numerisch gelöst. Das dabei zugrundegelegte Modell für die Mizellkinetik entspricht einem Bildungs-Auflösungs-Mechanismus. Es wird der Einfluß von Parametern wie Mizellkonzentration, Assoziationsgrad, Geschwindigkeitskonstanten der Mizellkinetik auf die Adsorptionskinetik diskutiert.
    Notes: Summary A model of diffusion controlled adsorption of surfactants from micellar solutions is given and numerically solved. The model used to describe the micelle kinetics corresponds to a formation-dissolution mechanism. Parameters like micelle concentration, aggregation number, rate constant of formation or dissolution of micelles influencing the adsorption process are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01524900
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    Paper (German National Licenses)
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