ISSN:
0044-2313
Keywords:
Trihalodithiatriazines
;
trihalotriazines
;
salt-, adduct-formation
;
X-ray structures
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Reactions of Trihalodithiatriazines and Trifluorotriazine with Halogen-Lewis-Acids.From the reaction of (XCN)(XSN)2 and MX5 (X = Cl, M = Sb; X = F, M = As) the corresponding salts [(XCN)(XSN)(SN)]+MX6- (2, 4) are obtained. (FCN)3 adds AsF5 to the nitrogen-bonded adduct (FCN)3 · AsF5 (6). The X-ray-structure of 6 is reported.
Notes:
Aus der Umsetzung von (XCN)(XSN)2 und MX5 (X = Cl, M = Sb; X = F, M = As) werden die entsprechenden Salze [(XCN)(XSN)(SN)]+MX6- (2, 4) erhalten. (FCN)3 addiert AsF5 zu dem stickstoffgebundenen Addukt (FCN)3 · AsF5 (6). Die Röntgenstrukturanalyse von 6 wird mitgeteilt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936191017
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