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Oxidation of Triphenylphosphine by Vanadium Oxytrichloride (2000)

Kanai, H. ; Osaka, S.

Springer

Reaction kinetics and catalysis letters 70 (2000), S. 105-112

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ISSN: 1588-2837

Keywords: Oxidation ; triphenylphosphine ; vanadium oxytrichloride ; solvent effect ; mechanism

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract A kinetic study on triphenylphosphine oxidation with VOCl3 was carried out in CCl4 and THF. The different mechanisms were elucidated; oxygen was activated dissociatively on solid vanadium complex in CCl4, while oxygen was coordinated molecularly on soluble vanadium complex in THF.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1010314800363

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