ISSN:
1573-2746
Keywords:
triple junctions
;
mobility of grain boundaries
;
non-equilibrium segregation
;
grain growth
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract We consider the steady state migration of the triple junction in the tricrystal with impurities which segregate strongly at the grain boundaries. If the mobility of impurities inside grain boundaries is much higher than the rate of impurity atoms jumps from the grain boundary into the bulk, the triple junction migration causes the divergence of the impurity content at the triple point. We show that this divergence can be relaxed either by the non-equilibrium segregation at the growing grain boundary or by the formation of the inclusion of the impurity-rich phase at the triple point. In the former case the dihedral angle at the triple point differs considerably from its equilibrium value and is strongly temperature-dependent. However, the triple junction cannot be described as an individual object with its own mobility. In the latter case of the cavity formation at the triple point the triple junction can be characterized by its own mobility. It is shown that the dependence of the triple junction migration rate on the driving force is approximately linear at the low migration rates and highly nonlinear at high migration rates. Moreover, there is the maximal allowable steady-state migration rate of the system “triple junction-inclusion”. For the higher migration rates the jerky motion of the triple junction occurs. Both models are in a good agreement with the experimental data.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1008729627921
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