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  • 1990-1994  (4)
  • Chemistry  (2)
  • two-tiered concept representation  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Machine learning 8 (1992), S. 5-43 
    ISSN: 0885-6125
    Keywords: Concept learning ; learning imprecise concepts ; inductive learning ; learning flexible concepts ; two-tiered concept representation ; flexible matching
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract This paper describes a method for learning flexible concepts, by which are meant concepts that lack precise definition and are context-dependent. To describe such concepts, the method employs a two-tiered representation, in which the first tier captures explicitly basic concept properties, and the second tier characterizes allowable concept's modifications and context dependency. In the proposed method, the first tier, called Base Concept Representation (BCR), is created in two phases. In phase 1, the AQ-15 rule learning program is applied to induce a complete and consistent concept description from supplied examples. In phase 2, this description is optimized according to a domain-dependent quality criterion. The second tier, called the inferential concept interpretation (ICI), consists of a procedure for flexible matching, and a set of inference rules. The proposed method has been implemented in the POSEIDON system, and experimentally tested on two real-world problems: learning the concept of an acceptable union contract, and learning voting patterns of Republicans and Democrats in the U.S. Congress. For comparison, a few other learning methods were also applied to the same problems. These methods included simple variants of exemplar-based learning, and an ID-3-type decision tree learning, implemented in the ASSISTANT program. In the experiments, POSEIDON generated concept descriptions that were both, more accurate and also substantially simpler than those produced by the other methods.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Machine learning 8 (1992), S. 5-43 
    ISSN: 0885-6125
    Keywords: Concept learning ; learning imprecise concepts ; inductive learning ; learning flexible concepts ; two-tiered concept representation ; flexible matching
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract This paper describes a method for learningflexible concepts, by which are meant concepts that lack precise definition and are context-dependent. To describe such concepts, the method employs atwo-tiered representation, in which the first tier captures explicitly basic concept properties, and the second tier characterizes allowable concept's modifications and context dependency. In the proposed method, the first tier, calledBase Concept Representation (BCR), is created in two phases. In phase 1, the AQ-15 rule learning program is applied to induce a complete and consistent concept description from supplied examples. In phase 2, this description is optimized according to a domain-dependent quality criterion. The second tier, called theinferential concept interpretation (ICI), consists of a procedure forflexible matching, and a set of inference rules. The proposed method has been implemented in the POSEIDON system, and experimentally tested on two real-world problems: learning the concept of an acceptable union contract, and learning voting patterns of Republicans and Democrats in the U.S. Congress. For comparison, a few other learning methods were also applied to the same problems. These methods included simple variants of exemplar-based learning, and an ID-3-type decision tree learning, implemented in the ASSISTANT program. In the experiments, POSEIDON generated concept descriptions that were both, more accurate and also substantially simpler than those produced by the other methods.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 7 (1993), S. 235-240 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Negative-ion fast-atom bombardment mass spectra of free and conjugated bile acids are dominated by [M — H]- pseudomolecularions. Collision-induced dissociations of these pseudomolecular ions give charge-remote fragmentation patterns which are useful for structural identification. Taurine (2-aminoethanesulrtionic acid)-conjugated bile acids have a high cross-section for charge-remote fragmentation, and give the most informative and intense spectra among the naturally occurring bile acids. In the present study, collision-induced dissociation spectra of bile acids derivatized with different aliphatic and aromatic aminosulphonates, and with 2-amlnoethyl hydrogen sulphate have been compared. All show charge-remote fragmentation patterns. Determination of the intensities of the fragment ions shows that the highest sensitivity is usually obtained with aromatic aininosulpho-nate derivatives.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 307-312 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Ammonium polyphosphate is shown to be an effective flame retardant for homopolymeric and selected fibre-forming copolymers of acrylonitrile. Compared with other phosphates and phosphorus-containing species, it significantly increases both limiting oxygen index and char levels. The mechanism of retardancy is shown to be both physical and chemical in character. When heated to 300°C, the polyphosphate melts and converts to polyphosphoric acid which acts as a physical barrier to surface polymer oxidation and promotes nucleophilic oligomerization of pendant, adjacent nitrile groups. A reduction in the activation energy of this first stage of acrylic polymer degradation suggests that the favoured decomposition route gives rise via oligomerization to char-promoting precursors. Char analyses indicate an empirical formula of C30H13N7P2, which compares favourably with that of a proposed phosphorylated, polynuclear, aromatic heterocyclic structure.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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