ISSN:
1432-0630
Schlagwort(e):
Kβ X-ray spectroscopy
;
silicon and quartz
;
valence electron states
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Maschinenbau
,
Physik
Notizen:
Abstract Kβ X-ray spectra of Si and SiO2 have been measured accurately with a double crystal spectrometer. The measuredKβ spectrum of silicon element was compared with calculations of the electronic density of states. Observed intensity distribution shows that thep-electrons predominate at the top of the valence band, and somep-like states extend to the middle of the valence band. According to MO calculations the most intensiveKβ line of SiO2 is 4t 2 (100), the 3t 2 (16) line is 17.9 eV lower, and 5t 2 (5) line 6.3 eV higher. In our measurements the energy differences are 13.0 and 4 eV, respectively, and intensities 30% and 3% from the main line.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00883750
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