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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 5 (1990), S. 143-154 
    ISSN: 1572-879X
    Keywords: NMR ; xenon ; coke ; zeolite ; extra-framework aluminium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Zeolites coking has been studied by129Xe-NMR technique. The distribution of the coke is heterogeneous on the supercage surface at low cokage level. When coking increases up to 10% the supercages are lined with coke and the residual internal volume consists of narrow channels. Beyond 10% the coke also affects the external surface of the zeolites, with the formation of coke microcavities between the crystallites. This technique has also enabled us to show the role of extra-framework Al in the cracking activity of zeolites.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 41 (1996), S. 143-148 
    ISSN: 1572-879X
    Keywords: gold particles ; zeolite ; TEM
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Two Au/NaHY systems examined by TEM were prepared using an autoreduction method of Au3+ by its ethylene diamine ligands. When about 10% of the cations are H+ the particle diameter distribution is found to be about 2 nm and homogeneous. If 75% of cations are H+ the gold particle distribution is centered around 3–4 nm. Gold particles are of good stability when exposed to H2 at 573 K for two days and the stability under O2 greater with the higher acidified zeolite.
    Type of Medium: Electronic Resource
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