ISSN:
1434-4475
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The complexes of pyridine-2-aldoxime (HPOX) and 6-methylpyridine-2-aldoxime (HMPX) with iron (II) thiocyanate of the type [Fe(L)(NCS)2] (L=HPOX and HMPX) have been prepared and characterized. A study of X-ray, magnetic, vibrational spectra (conventional and far-infrared), electronic spectra andMössbauer spectra has indicated that these complexes have polymeric, pseudo octahedral, coordination geometry with linear bridging thiocyanate ligands. The electronic spectra of mono complexes show a larger, low symmetry, ligand field than that present in [Fe(L)2(NCS)2] complexes. UnperturbedMössbauer spectra show a large quadrupole splitting, ΔE Q, and smaller isomer shift values in these iron (II) thiocyanate complexes. The magnetically perturbedMössbauer spectra of these iron(II) thiocyanate complexes at room temperature show that the principal component of the electric field gradient tensor is positive and corresponds to ad xy (5B2) ground state.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00906353
Permalink