Bibliothek

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Industrial and engineering chemistry 11 (1972), S. 543-546 
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Industrial and engineering chemistry 17 (1978), S. 373-374 
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    ISSN: 1572-8757
    Schlagwort(e): coalbed methane ; coal (porous structure, micropores) ; adsorption (of xenon, carbon dioxide, methane) ; Xe-129 NMR spectroscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract An experimental and theoretical study of adsorption and diffusion of carbon dioxide and methane in coals of widely varying rank was carried out. Low pressures adsorption isotherms of CO2 were obtained and analyzed using Dubinin's theory of volume filling of micropores. High-pressure adsorption isotherms of CH4 were obtained and analyzed using tracer pulse chromatography in conjunction with an appropriate adsorption/diffusion model. A preliminary129Xe NMR analysis of chemical shifts experienced by xenon atoms in particles of different sizes is also reported. The heretofore undocumented and/or underestimated effects of activated diffusion of CO2 at 273–298 K complicate the elucidation of the true microporous structure of coals, especially its dependence on coal rank. Activated diffusion of both CO2 and methane at room temperature does not allow reliable estimates of coalbed gas content to be made. A model of an interconnected network of pores which includes randomly distributed, numerous and ultramicroporous constrictions (at any size scale) is consistent with all these experimental and theoretical findings.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 551-557 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A new method of predicting adsorption equilibria for multicomponent liquid solutions on solids has been developed which combines the thermodynamic and kinetic treatments of liquid adsorption. Multicomponent equilibria can be predicted using parameters obtained from binary adsorption data. The method requires the adsorbent capacities, the bulk and surface phase activity coefficients, and the binary adsorption equilibrium constants. The calculation procedure is simpler than other available methods. Predictions are made for the mixture of benzene, ethyl acetate, and cyclohexane on activated carbon at 303 K. The predictions are in quantitative agreement with published experimental data for this system.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1138-1145 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A recently developed error-in-variables method of calculating regression parameters was applied to the modeling of gas-solid adsorption equilibria. The method accounts for error in all experimental variables in the regression calculations. Regression coefficients from pure component data calculated by the new method were used to predict multicomponent equilibria. The multicomponent predictions using pure component parameters calculated by the error-in-variables method were more accurae than predictions using parameters calculated by conventional least-squares regression.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1077-1085 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A perturbation chromatography technique using radiotracer gases has been developed to determine the adsorption equilibrium constants and diffusivities in molecular sieves. The ethane and ethylene 13X molecular sieve systems were studied in regions of high concentration. The data obtained by this technique are shown to be in agreement with equilibrium data obtained by static methods and with kinetic data obtained by adsorption uptake and chromatographic methods, but not with kinetic data obtained using NMR techniques. The tracer-pulse chromatographic technique is much more efficient for obtaining gas adsorption equilibria and intraparticle diffusivities and is considerably easier to adapt to wide pressure and temperature ranges than the conventional methods.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 515-520 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental results for the adsorption of the binary gas mixtures oxygen-nitrogen, oxygen-carbon monoxide and nitrogen-carbon monoxide on two synthetic zeolites are reported. In all of these experiments the temperature was -200°F. and the total pressure was 1 atm. Also reported are the isotherms for the three pure gases on the two zeolites at -200°F. The results indicate that these zeolites have a surface selectivity which is independent of any sieving effect based on the size of the adsorbed molecules. It does not appear that the strong separations obtained can be explained in terms of the van der Waals forces which are generally believed to be dominant in physical adsorption. The available methods of predicting binary adsorption data from the pure gas isotherms have been examined.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 8
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 268-277 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: New equations for the physical adsorption of gases on solids have been developed based on the vacancy solution model of adsorption in conjunction with the Flory-Huggins activity coefficient equations. The isotherm equation contains three regression parameters: a Henry's law constant, the limiting amount of adsorption, and a gas-solid interaction term. Pure-gas data over a range of temperature can be correlated using only five parameters. Gas-mixture equilibria can be predicted using only the parameters obtained from the pure-gas data. Pure-component, binary, and ternary adsorption equilibrium data on activated carbons, silica, and zeolites over a wide range of conditions have been used to evaluate the model. The results show that, except for a few systems, this model predicts gas-mixture equilibria better than any other model.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 9
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 2075-2081 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The vacancy solution model of adsorption which uses an activity coefficient equation of the Wilson form has been improved (1) by incorporating temperature dependency into the model, and (2) by development of a functional relationship between the adsorbate-adsorbate binary interaction parameters. This reduces the number of regression parameters and improves the predictive capabilities of the model. Comparisons of this improved model with the Flory-Huggins activity coefficient form of the vacancy solution model are presented for binary and ternary systems. For a priori predictions from pure-component data, the Flory-Huggins form is recommended. If experimental binary data are available for all pairs, the form that most accurately correlates the binary data should be used to predict higher-order systems.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 1527-1532 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: According to the Flory-Huggins theory for polymer blends, the polymerpolymer interaction parameter, χ23, must be positive for incompatible polymers. Previous studies of the incompatible ternary system chloroform-polystyrerne-butadiene rubber yielded negative values of χ23 using a solution method based on the Flory-Huggins theory with the chloroform-butadiene rubber interaction parameter used as input. An alternate solution method using the chloroform-polystyrene interaction parameter as input has been used to obtain positive values of χ23 for this incompatible system. This variation in results indicates that the interaction parameters obtained using the Flory-Huggins theory are not physically meaningful. They are, however, useful as correlating parameters. Both sets of results, although quite different, are shown to correlate the experimental data identically well. In addition, the appropriate equations are presented for the case where one of the solvent-polymer interaction parameters is concentration dependent.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...