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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of organic chemistry 30 (1965), S. 1260-1262 
    ISSN: 1520-6904
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6320-6322 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Neutron scattering and specific heat measurements have been carried out on a series of NdBa2Cu3O6+x powder samples with varying oxygen concentrations (x=0.94, 0.78, 0.45, 0.3, 0.13) in order to study the effects of oxygen on the magnetic order of Nd. For our highest oxygenated superconducting NdBa2Cu3O6.94 (Tc(approximately-equal-to)92 K), three-dimensional (3D) long range order develops below TN(approximately-equal-to)0.53 K, with a spin configuration which is antiferromagnetic along all three crystallographic axes. For a small reduction of oxygen to x=0.78, we observe drastic effects on the Nd order; 3D order is inhibited and only short range 2D correlations are found at low temperature. However, the 2D correlations develop at a much higher temperature, near 1.5 K. At (nonsuperconducting) x=0.45, the 3D magnetic order is better developed at low temperature, yet long range order still does not occur. For x=0.3, 3D long range magnetic order of the Nd ions is reestablished, developing below TN(approximately-equal-to)1.5 K, three times that of the fully oxygenated material. All of these ordering temperatures are much higher than what is expected based on dipolar interactions alone, and this coupled with our experimental results indicates that exchange interactions play an essential role, and are strongly influenced by the chain layer oxygen.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 4530-4532 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Polarized and unpolarized neutron scattering techniques along with x-ray diffraction have been used to study the magnetic and structural properties of a single crystal of Nd2CuO4. Long-range magnetic order of the Cu moments develops at TN=245 K, with a simple antiferromagnetic configuration of spins as found in La2NiO4, while the spin directions may be either collinear or noncollinear. Additional abrupt transitions are observed at 75 and 30 K, in which spin reorientations take place. Bragg peaks associated with the crystal structure are found at the same positions as the magnetic Bragg peaks, and indicate that a small distortion of the basic tetragonal structure has occurred above 300 K. At low temperatures the Nd moments also order antiferromagnetically (TN=1.5 K), while an additional transition of a continuous nature is observed at 150 mK.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6326-6328 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have used neutron diffraction techniques to study the field dependence of the magnetic ordering of Cu spins in R2CuO4 (R=Nd,Sm) in order to distinguish between the proposed collinear and noncollinear spin structures. In the proposed collinear spin structure, there are two separate domains with the spins either along the (110) or along the (11¯0) directions, while in the noncollinear model there is a single domain with the alternate-layer spins along the (100) and (010) directions, respectively. If a magnetic field is applied along the (11¯0), strong hysteresis effects are anticipated for the collinear spin structure due to domain repopulation, while such effects are not expected for the noncollinear spin structure. Our field dependent data do not show any hysteresis effects associated with the pure Cu ordering, which strongly suggest that the noncollinear spin structure is correct for the magnetic spin configuration of the Cu spins in both compounds. Hysteresis effects in a field are observed in Sm2CuO4 near and below the Sm ordering temperature, and these are most likely caused by the interaction between Sm and Cu sublattices.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 5751-5753 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Neutron diffraction has been used to study the magnetic fluctuations and long range order of the Dy ions in single crystals of superconducting DyBa2Cu3O7. The temperature dependence of the rod of scattering, characteristic of 2D behavior, has been measured above and below the 3D Néel temperature (TN (approximately-equal-to) 0.9 K). This rod intensity is observed to increase as the temperature decreases until TN is reached, and then the intensity decreases rapidly below TN. The 2D magnetic correlation length, which is obtained from measurements of the width of the rod, grows continuously with decreasing temperature, then reaches a resolution-limited maximum at the Néel temperature when long range magnetic order sets in. At low T, two separate types of simple 3D antiferromagnetic structures are found, one characterized by a wave vector of (1/2 1/2 0), and the other by (1/2 1/2 1/2). We believe the two types of order occur because the (dipolar) energies for these two configurations are nearly identical. This behavior is analogous to the 2D and 3D magnetic order of Er observed in ErBa2Cu3O7.
    Materialart: Digitale Medien
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  • 6
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The temperature dependence of the magnetic susceptibility χ(T) and heat capacity C(T), the temperature and field dependence of the magnetization M(T,H), and neutron diffraction have been measured in the tetravalent perovskite system BaPrO3. A clear anomaly, observed in C(T), χ(T), and neutron scattering data at 11.7 K is attributed to antiferromagnetic alignment of Pr. Magnetization indicates that this ordering is insensitive to magnetic fields with TN being independent of H for H〈12 T. High-field isotherms show an upward kink in slope at 12.7 T independent of temperature for T〈9.5 K, suggestive of a spin reorientation transition. 119Sn Mössbauer data for BaPr0.95Sn0.05O3 indicate a quadrupole splitting at 300 K that broadens below TN due to a hyperfine field.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 5369-5371 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Conventional spin wave theory works remarkably well in describing the spin dynamics of both Invar and non-Invar isotropic ferromagnets, with the important exception that for Invar systems the magnetization decreases much more rapidly with temperature than can be explained based on the measured spin wave dispersion relations. We have been carrying out triple-axis polarized inelastic neutron scattering experiments on the amorphous ferromagnets Fe86B14 (Invar system) and Fe40Ni40P14B6 (METGLAS(large-closed-square) 2826) in order to separate the longitudinal magnetic fluctuations from the transverse (spin wave) excitations, and thereby determine if the presence of longitudinal excitations might resolve this discrepancy. The present measurements exhibit longitudinal excitations below Tc, but in both materials. Possible interpretations of the results are discussed.
    Materialart: Digitale Medien
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  • 8
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Ferrous trimethylammonium chloride (FeTAC) is a member of a family of compounds that consist of chains of bihalide-bridged metal ions aligned along the b axis of the orthorhombic unit cell. The chains are connected in (bc) planes by hydrogen bonding of the waters of hydration; these planes are isolated along the a axis by the large trimethylammonium groups. FeTAC orders three dimensionally below TN=3.16 K, with the moments, which are canted from the b axis by ∼20°, coupled ferromagnetically along the b axis and staggered along the [101] direction. The order parameter follows the exact Onsager solution for a rectangular 2D Ising lattice below T/TN≈0.95, with ratio for the two in-plane magnetic exchange constants of 1.3×10−3. However, quasielastic scattering measurements in the vicinity of TN show that the correlations do not evolve as do those of the 2D Ising antiferromagnets ErBa2Cu3O7 and K2CoF4. Above TN, magnetic excitations along the b axis that follow the dispersion relation of a 1D ferromagnet with a gap of 3.7 meV have been observed.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 4866-4868 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Neutron diffraction techniques have been used to study the magnetic order of the Cu ions in a single crystal of Sm2CuO4. The measurements revealed the development of long-range magnetic order of the Cu moments at TN = 280 ± 1 K, with a relatively simple antiferromagnetic configuration of spins as found in Nd2CuO4 and Pr2CuO4. However, the spin directions in Sm2CuO4 are rotated by 90° from the spin directions in Nd2CuO4 and Pr2CuO4. The detailed spin structure can be either collinear or noncollinear, and in these tetragonal systems it is not possible to distinguish between them with the present neutron diffraction data on multidomain samples. Our measurements demonstrate that there are no spin reorientations below the Néel temperature, in contrast to the behavior found for Nd2CuO4.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5857-5859 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Neutron diffraction has been used to investigate the magnetic order of RNi2B2C. For R=Er the system orders antiferromagnetically at TN=6.8 K, and this long range order coexists with superconductivity (Tc=11 K). The magnetic structure is an incommensurate, transversely polarized spin-density-wave state, with the modulation wave vector δ along the a axis and the moments along b. δ has a temperature-independent value of 0.5526 (2π/a), with the structure squaring up at low temperatures. For R=Ho the moments also prefer to reside in the a–b plane, but initially an incommensurate c-axis spiral state forms upon cooling, with TN≈TC≈8 K. This c-axis spiral consists of ferromagnetic sheets of holmium moments in the a–b plane, but with each sheet rotated by ∼163° as one proceeds along the c axis. Small a-axis peaks are also observed above the reentrant superconducting transition over a narrow temperature range, but the c-axis peaks dominate. Just below the reentrant transition at ∼5 K the magnetic system locks-in to a simple commensurate antiferromagnetic structure, which permits superconductivity to be restored. The c-axis spiral, the a-axis component, the commensurate antiferromagnetic structure, and the superconducting phase are all in a delicate balance energetically, and this balance may be easily shifted by subtle changes in composition, magnetic field, and pressure. DyNi2B2C orders antiferromagnetically at TN=11 K, with the same commensurate antiferromagnetic structure as found for the holmium material at low temperature. The existence of superconductivity in some samples of DyNi2B2C is consistent with the antiferromagnetic structure observed. © 1996 American Institute of Physics.
    Materialart: Digitale Medien
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