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  • 1
    Digitale Medien
    Digitale Medien
    Reaction of acetonitrile and chlorine atoms
    Amsterdam : Elsevier
    Journal of Photochemistry 24 (1984), S. 315-322 
    Details
    ISSN: 0047-2670
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    URL: http://linkinghub.elsevier.com/retrieve/pii/0047-2670(84)80013-1
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  • 2
    Digitale Medien
    Digitale Medien
    The Hg6(^3P"1) photosensitized reactions of 1-methyl- cyclopentene
    Amsterdam : Elsevier
    Journal of Photochemistry 4 (1975), S. 299-305 
    Details
    ISSN: 0047-2670
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    URL: http://linkinghub.elsevier.com/retrieve/pii/0047-2670(75)87006-7
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  • 3
    Digitale Medien
    Digitale Medien
    The chlorine-atom-sensitized oxidation of chloroform
    Amsterdam : Elsevier
    Journal of Photochemistry 14 (1980), S. 19-37 
    Details
    ISSN: 0047-2670
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    URL: http://linkinghub.elsevier.com/retrieve/pii/0047-2670(80)85065-9
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  • 4
    Digitale Medien
    Digitale Medien
    Mercury-photosensitized cis-trans isomerization of olefins in the gas phase physical chemistry experiments for the advanced undergraduate laboratory
    Amsterdam : Elsevier
    Journal of Photochemistry 15 (1981), S. 67-84 
    Details
    ISSN: 0047-2670
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    URL: http://linkinghub.elsevier.com/retrieve/pii/0047-2670(81)85018-6
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  • 5
    Digitale Medien
    Digitale Medien
    Rate of recombination of C"6F"1"0Cl radicals in the gas phase
    Amsterdam : Elsevier
    Chemical Physics Letters 5 (1970), S. 183-185 
    Details
    ISSN: 0009-2614
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    URL: http://linkinghub.elsevier.com/retrieve/pii/0009-2614(70)80038-0
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  • 6
    Digitale Medien
    Digitale Medien
    Chlorine-photosensitized reactions in the Cl2 + O2 + 1,1,1,2-C2H2Cl4 system (1976)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 8 (1976), S. 11-22 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The gas-phase photochlorination (λ = 436 nm) of the 1,1,1,2-C2H2Cl4 has been studied in the absence and the presence of oxygen at temperatures between 360 and 420°K. Activation energies have been estimated for the following reaction steps: \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{*{20}c} {{\rm CCl}_3 {\rm CHCl}^{\rm .} + {\rm Cl}_2 \to {\rm CCl}_3 {\rm CHCl}_{\rm 2} + {\rm Cl}^{\rm .}} & {E_3 = (4.6 \pm 0.4){\rm kcal/mole}} \\ \end{array}$$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{*{20}c} {{\rm CCl}_3 {\rm CHCl}^{\rm .} \to {\rm CCl}_2 {\rm CHCl} + {\rm Cl}^{\rm .}} & {E_4 = (20.6 \pm 1.4){\rm kcal/mole}} \\ \end{array}$$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{*{20}c} {{\rm CCl}_3 {\rm CHClO}_{\rm 2} {\rm CHClCCl}_3 \to 2{\rm CCl}_3 {\rm CHClO}^{\rm .}} & {E_{15} = (33.5 \pm 3.0){\rm kcal/mole}} \\ \end{array}$$\end{document}The dissociation energy D(CCl3CHCl—O2) ± (24.8 ± 1.5) kcal/mole has also been estimated from the difference in activation energy of the direct and reverse reactions The mechanism is discussed and the rate parameters are compared to those obtained for a series of other chlorinated ethanes.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550080103
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  • 7
    Digitale Medien
    Digitale Medien
    Competitive chlorination-dehydrochlorination of 1,1,1,2-C2H2Cl4 (1979)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 117-124 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The competitive photochlorination and chlorine photosensitized dehydrochlorination of 1,1,1,2-C2H2Cl4 have been studied over the temperature range of 349.4-404.5 K after less than 1% conversion. The results are discussed and a value of \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_{4A} (\sec ^{ - 1}) = (11.6\pm 0.6) - (16,400\pm 1000)/4.58T $$\end{document} is proposed for the reaction \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CCl}_{\rm 3} {\rm CHCl}\mathop \to \limits^{(4{\rm A)}} {\rm CCl}_{\rm 2} {\rm CHCl + Cl} $$\end{document} This result, combined with existing thermochemical data, indicates that there is no evidence of an activation energy for the addition of a Cl atom on the most chlorinated carbon in trichloroethylene: in that case the selectivity of the addition of Cl on the less chlorinated carbon should not depend on temperature.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550110203
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  • 8
    Digitale Medien
    Digitale Medien
    Chlorine-photosensitized oxidations of chloroethanes and chloroethylenes in the gas phase (1971)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 3 (1971), S. 89-96 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Long-chain chlorine-photosensitized oxidation has been observed in the gas phase at about 355°K for 1,1,2,2- and 1,1,1,2-C2H2Cl4, C2HCl5, and C2Cl4 but not for C2H6, 1,2-C2H4Cl2, 1,1,1-C2H3Cl3, C2H4, and 1,2-C2H2Cl2. This is shown to depend on the exothermicity of the dissociation of the chloroethoxy radicals which must be involved in each reaction system.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550030108
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  • 9
    Digitale Medien
    Digitale Medien
    Termolecular reaction of nitrogen monoxide and oxygen: A still unsolved problem (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 835-848 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The oxidation of nitrogen monoxide has been studied extensively between 226 and 758 K at pressures of NO and O2 ranging from about 0.2 to 30 torr. It has been shown that (i) the reaction is properly first order against oxygen and second order against nitrogen monoxide, as well under initial conditions as during the course of the reaction; (ii) the termolecular rate constant, k, first decreases with increasing temperature and reaches a minimum value at 600 K; (iii) the transition state theory is unable to describe this behavior correctly, (iv) under the present experimental conditions k can be represented either by \documentclass{article}\pagestyle{empty}\begin{document}$$ \log _{10} k({\rm l}^{\rm 2} {\rm mol}^{ - 2} {\rm s}^{ - 1}) = - (5.18 \pm 1.00) + (2.70 \pm 0.25){\rm log}_{{\rm 10}} T + (700 \pm 50)/T $$\end{document} or by \documentclass{article}\pagestyle{empty}\begin{document}$$ k({\rm l}^{\rm 2} {\rm mol}^{ - 2} {\rm s}^{ - 1}) = (350 \pm 100)10^{(390 \pm 50)/T} + (8000 \pm 2000)10^{ - (440 \pm 50)/T} $$\end{document} The latter equation is compatabile with a multiple-step mechanism.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550170805
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  • 10
    Digitale Medien
    Digitale Medien
    Reaction of chlorine with bromine (1974)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 6 (1974), S. 395-400 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Different possible mechanisms for the gas phase reaction of formation of bromine chloride from bromine and chlorine are discussed. The rate of the reaction has been deduced from photometric measurements in conventional static reactors of surface-to-volume ratio ranging between 0.6 and 3 cm-1, at temperatures between 51 and 113°C. Experimental data show that (1) the observed reaction is predominantly heterogeneous, and (2) the homogeneous reaction must proceed by an atomic chain mechanism initiated by Br atoms.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550060309
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