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Digitale Medien

Bulk viscosity of polymeric systems (1959)

Hirai, Nishio ; Eyring, Henry

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 37 (1959), S. 51-70

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ISSN: 0022-3832

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The theory of bulk viscosity as developed for the liquid state was applied to amorphous high polymeric systems. The isothermal volume contraction, the dependence of shear viscosity, and the fictive temperature of quenched high polymeric substances are all related to the bulk viscosity and explained by this theory. Simple representations are given for compressibility, bulk modulus, shear modulus, thermal expansion coefficient, and heat capacity, all of which are necessary to discuss the bulk viscosity. The theory has been compared with the experimental results for natural rubber, polystyrene, polyisobutylene, and polyester.

Zusätzliches Material: 1 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1959.1203713104

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Digitale Medien

Modeling of biological reactions (1981)

Ma, Shao-mu ; Eyring, Henry ; Ueda, Issaku ; [weitere]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 13 (1981), S. 913-923

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ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Cell membranes consist of lipid bilayers in which proteins are embedded. Many cell functions are carried out at the cell boundary which interface with water. Here we describe the response to an anesthetic of a lipid bilayer and of an enzyme separately. While both systems are markedly affected by anesthetics at appropriately high concentrations, the result at the clinical concentrations seems best explained as principally an effect on the protein somewhat accentuated by its presence in the lipid bilayer. Thus the lipoprotein complex seems to have the properties of the protein alone, except with somewhat greater induced sensitivity due to the lipid matrix in which it is immersed.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550130914

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