ISSN:
1573-9171
Schlagwort(e):
electroreduction
;
alkynyl halides
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract Reduction of phenylethynyl halides PhC≡CHal (Hal = I (1), Br (2), Cl (3)), diiodoacetylene (4), (phenylethynyl)triphenylphosphonium bromide (5), and related compounds in THF was studied by means of cyclic voltammetry using a glassy-carbon electrode. Compounds1–5 are reduced with cleavage of the C-Hal bond, and the reduction potentials increase in the order3 〈2 〈1 〈4 〈5.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00707244
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