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Digitale Medien

Tautomerism and vapor-phase transformations of 2-hydroxytetrahydrofuran (2000)

Lebedev, A. ; Leite, L. ; Fleisher, M. ; [weitere]

Springer

Chemistry of heterocyclic compounds 36 (2000), S. 775-778

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Details

ISSN: 1573-8353

Schlagwort(e): 2-hydroxytetrahydrofuran ; 4-hydroxybutanal ; 2,3-dihydrofuran ; tautomerism ; dehydration ; AM1 method ; concerted mechanism

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The relative stability of 2-hydroxytetrahydrofuran and the tautomeric 4-hydroxybutanal was determined by the semi-empirical AM1 method. It was concluded that the cyclic tautomer predominates in the gas phase at 25°C. Vapor-phase dehydration of 2-hydroxytetrahydrofuran in the presence of porcelain and silica gel L leads to a quantitative yield of 2,3-dihydrofuran.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02256908

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