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Estimation of the ground state correlation energy for isoelectronic series of 2 to 20 electrons (1987)

Rashid, K. ; Fricke, B. ; Heinemann, D. ; [weitere]

Springer

The European physical journal 7 (1987), S. 139-146

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Details

ISSN: 1434-6079

Schlagwort(e): 31.20.Ej ; 31.20.Tz

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract Correlation energies for all isoelectronic sequences of 2 to 20 electrons andZ=2 to 25 are obtained by taking differences between theoretical total energies of Dirac-Fock calculations and experimental total energies. These are pure relativistic correlation energies because relativistic and QED effects are already taken care of. The theoretical as well as the experimental values are analysed critically in order to get values as accurate as possible. The correlation energies obtained show an essentially consistent behaviour fromZ=2 to 17. ForZ〉17 inconsistencies occur indicating errors in the experimental values which become very large forZ〉25.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01384579

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