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High resolution photofragment spectroscopy of the gas phase methyl iodide ion (1989)

Lingbing, Chen ; Figger, H. ; Quint, W.

Springer

The European physical journal 13 (1989), S. 61-67

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Details

ISSN: 1434-6079

Schlagwort(e): 33.20.K ; 33.80.G ; 36.90

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract Photodissociation spectra of the molecular ion CH3I+ were obtained with a three stage quadrupole mass spectrometer. Starting from the $$\tilde X^2 E_{3/2} $$ ground state, theÃ 2 E 1/2 state was excited with a stilbene 3 cw dye laser. This state predissociates to CH + 3 +I. Measuring the intensity of the CH + 3 fragment ions as a function of the wavelength of the exciting laser, a spectrum showing vibrational and rotational structure was obtained. The vibrational structure was assigned to three progressions ofv 3 and new vibrational frequencies were determined. From a computer simulation of the (0, 1, 10) band rotational constants were derived. In particular, their dependence on the vibrationv 3 was studied.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01437344

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