ISSN:
0030-493X
Schlagwort(e):
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
A Fourier transform-ion cyclotron resonance study of thioacyl compounds as binary mixtures with unsaturated hydrocarbons has revealed that thioacetylium ions CH3CS+ generated by electron fragmentation fail to thioacyl-ate even the most reactive aromatic hydrocarbons. Among the hydrocarbons studied, only 3-hexyne and 2,4-dimethyl-2,5-hexadiene were observed to react with CH3CS+. Apart from proton-transfer reactions, the major ionic reaction of thioesters with arenes, alkynes and alkenes is condensation of the molecular ion of one component, usually the ester, with a neutral molecule of the other, resulting in the cleavage of the S—Calkyl bond of the thioester. The nature of this reaction is discussed and a possible mechanism is suggested.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/oms.1210230705
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