ISSN:
1435-1536
Schlagwort(e):
Contactangle
;
carbonfiber
;
wettingforce
;
surfacefreeenergy
;
Augerelectronspectroscopy
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
Notizen:
Abstract The surface free energy of polyacrylonitrile carbon fibers was investigated by using the Wilhelmy technique. The difference in surface free energy between immersion and emersion was observed for the carbon fiber pyrolyzed at 2500 °C. In contrast, the hysteresis disappeared with repyrolyzation of the carbon fibers at 3000 °C. Auger electron spectroscopic analysis indicated that the surface of the latter carbon fiber (repyrolyzed at 3000 °C) consisted of the basal planes of graphite. Rough surface topography of the carbon fiber repyrolyzed at 3000 °C, as observed by scanning electron microscope, did not affect the hysteresis. Therefore, the contact angle hysteresis was attributed to the chemical adsorbants on the activation sites of the fiber surfaces, as detected by Auger electron spectroscopy.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01524372
Permalink
