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Digitale Medien

The Chatt cycle and the mechanism of enzymic reduction of molecular nitrogen (1996)

Pickett, Christopher J.

Springer

JBIC 1 (1996), S. 601-606

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ISSN: 1432-1327

Schlagwort(e): Key words Nitrogenase ; Hydrogen evolution ; Molybdenum ; Hydrides ; Electron transfer

Quelle: Springer Online Journal Archives 1860-2000

Thema: Biologie , Chemie und Pharmazie

Notizen: Abstract The Chatt Cycle is a hypothetical model for the mechanism of nitrogenase action at the atomic level and is based upon reactions of certain well-defined molybdenum compounds. The proton and electron-transfer chemistry of the cycle is reviewed, revised and extended. An explanation for general and obligatory hydrogen evolution by the nitrogenase system is advanced; this involves carboxylate acting as a tethered leaving group at the Mo centre and the formation of mono-, di- and tri-hydric intermediates. The chemical model is integrated with the biochemical model proposed by Lowe and Thorneley.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/s007750050099

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