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  • Physical Chemistry  (4)
  • COPD  (1)
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  • 1
    Digitale Medien
    Digitale Medien
    Domains, constructs and the development of the breathing problems questionnaire (1994)
    Springer
    Quality of life research 3 (1994), S. 245-256 
    Details
    ISSN: 1573-2649
    Schlagwort(e): Constructs ; COPD ; domains ; validation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Abstract Health-related quality of life (QoL) questionnaires are commonly developed as content valid instruments with conventionally defined domain subscales. We contrasted content valid domain subscales with construct valid construct subscales and developed a 13-domain QoL questionnaire, the Breathing Problems Questionnaire (BPQ), for patients with chronic bronchitis. In a series of studies, we examined the constructs relevant to COPD patients' experience of health. First, we provided psychometric evidence that items in the BPQ form two distinct groups: functional problems and negative evaluations. Second, we showed that problems were significantly more correlated with morbidity whereas negative evaluations were significantly more correlated with neuroticism. Third, we showed that negative evaluations correlated with neuroticism whereas positive evaluations (measured by the Satisfaction with Illness Scale) correlated with extraversion. Patients are more likely to make positive evaluations of their Illness when they recognize that they are seriously ill. Most of the BPQ domains are subcategories of the construct of problems: both domains and construct classifications provide useful information.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00434898
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  • 2
    Digitale Medien
    Digitale Medien
    A shock tube study of the reaction of methyl radicals with hydroxyl radicals (1991)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 23 (1991), S. 1017-1033 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ± 0.3) × 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experimental data and calculations. Several possible reaction channels are discussed, and although products were not monitored, it seems probable, on the basis of other work and theoretical estimates, that the primary mechanism (≃75%) for the removal of OH by CH3 at these conditions is their combination to form CH3OH. Rate coefficients of (5.3 ± 0.8) × 1012 and (9.0 ± 1.4) × 1012 cm3/mol-s were measured for the reactions of OH with acetone and ethane, respectively, at the same temperature and pressure.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550231106
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  • 3
    Digitale Medien
    Digitale Medien
    A shock tube study of the reactions of the hydroxyl radical with several combustion species (1991)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 23 (1991), S. 1075-1094 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Reactions of the hydroxyl radical, OH, with several organic species of interest in combustion chemistry have been studied near 1200 K and 1 atm in shock tube experiments in which UV absorption was used to monitor the OH concentration. Rate coefficients were measured for the reactions of OH with 2,3-dimethylbutane, isooctane, neooctane, ethylene, propylene, acetylene, formaldehyde, methanol, and ethanol. The values were found to be (in units of 1012 cm3/mol-s): 21, 22, 18, 2.6, 9.6, 0.28, 12, 5.2, and 5.3. These measured values are compared with previous experimental results and, where appropriate, transition-state theory calculations.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550231203
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  • 4
    Digitale Medien
    Digitale Medien
    A shock tube study of the reaction of the hydroxyl radical with propane (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 1557-1566 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The rate coefficient for the reaction of the hydroxyl radical, OH, with propane has been measured at 1220 K in shock tube experiments, and a value of (1.58 ± 0.24) × 1013 cm3/mol s was obtained. This measured value is compared with previous experimental results and a transition-state theory calculation.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550161209
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  • 5
    Digitale Medien
    Digitale Medien
    A shock tube study of the reaction of the hydroxyl radical with H2, CH4, c-C5H10, and i-C4H10 (1989)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 21 (1989), S. 485-498 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Reactions of the hydroxyl radical, OH, with several reactants have been studied near 1200 K in shock tube experiments in which UV absorption was used to monitor the OH concentration. The values of the rate coefficients were found to be 2.7 × 1012, 2.6 × 1012, 2.8 × 1013, and 1.26 × 1013 cm3/mol-s for the reactions of OH with hydrogen, methane, cyclopentane, and isobutane, respectively. These measured values are compared with previous experimental results and transition-state theory calculations.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550210702
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