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Generalized Rouse-Zimm theory for polymer solutions (1981)

Hess, W. ; Jilge, W. ; Klein, R.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 849-862

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Details

ISSN: 0098-1273

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Generalized Rouse-Zimm equations are derived using a local equilibrium ansatz for the segment distribution function. The relaxation frequencies depend on excluded-volume effects and other interactions such as entanglement in semidilute solutions through exact static correlation functions. For the case of ring polymers general expressions are given for diffusion coefficients and mean-square displacements. By use of the “blob” model, explicit results are presented for a dilute good-solvent system.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1981.180190512

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