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Digitale Medien

Doubly-charged gas phase cations (1986)

Shields, G. C. ; Moran, T. F.

Springer

Theoretical chemistry accounts 69 (1986), S. 147-159

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ISSN: 1432-2234

Schlagwort(e): Doubly-charged cations ; Stabilities and reactivities

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Unique features of doubly-charged stable organic ions are examined and the results correlated with experimental observations. Self-consistent field molecular orbital methods are used to compute structures and stabilities of CnH 2 2+ (n=2–9) ions which are prominent in electron impact ionization of hydrocarbon molecules. A simple curve crossing model is employed to rationalize charge transfer reactions of these ions.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00527686

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