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Digitale Medien

Comparison of Electrolytic Conductivity Theories: Performance of Classical and New Theories (2000)

Bianchi, Hugo L. ; Dujovne, Irene ; Fernández-Prini, Roberto

Springer

Journal of solution chemistry 29 (2000), S. 237-253

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ISSN: 1572-8927

Schlagwort(e): Conductivity ; electrolytes ; electrolyte theory

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Conductivity equations, based on the mean spherical approximation (MSA), haverecently been derived. We compare their performance with that of classicalequations at the level of experimental uncertainty using conductivity data forsome typical electrolyte solutions. For symmetrical electrolytes, the pictureisconsistent showing a better performance for the classical equations. The Leeand Wheaton equation also shows advantages at moderate concentrations. Forunsymmetrical electrolytes, the differences between MSA and classical equationsis larger. There is, however, an inherent inconsistency with the equilibriuminformation, which cannot be resolved at present.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1005198316676

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