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Tunneling dynamics of one- and two-dimensional cubic oscillators with randomly fluctuating harmonic force constants: A numerical experiment This paper is dedicated to Professor Mihir Chowdhury on the occasion of his 60th birthday. (1997)

Sarkar, Pranab ; Bhattacharyya, S. P.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 64 (1997), S. 403-409

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Details

ISSN: 0020-7608

Schlagwort(e): tunneling dynamics ; tunneling through fluctuating barrier ; tunneling rate ; time-dependent cubic oscillator ; random cubic oscillator ; Chemistry ; Theoretical, Physical and Computational Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The tunneling dynamics of one- and two-dimensional cubic oscillators having randomly fluctuating harmonic force constants (Kt) are studied numerically by invoking the time-dependent Fourier grid Hamiltonian method. The influence of the frequency and strength of the fluctuation on the tunneling probability and tunneling rate is analyzed. The predicted nature of the influence depends upon whether the cubic oscillator is one- or two-dimensional. The possibility of mapping the proton-transfer systems onto the present model is explored. © 1997 John Wiley & Sons, Inc. Int J Quant Chem 64: 403-409, 1997

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

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