ISSN:
1600-5759
Quelle:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Thema:
Chemie und Pharmazie
,
Geologie und Paläontologie
,
Physik
Notizen:
The title compound, μ-aqua-1:2κ2O-pentaaqua-1κ2O,2κ3O-μ-3,6-bis(6-methyl-2-pyridyl)pyridazine-1κ2N1,N6:2κ2N2,N3-chloro-1κCl-dinickel(II) trichloride trihydrate, [Ni2Cl(C16H14N4)(H2O)6]Cl3·3H2O, consists of two NiII atoms, a 3,6-bis(6-methyl-2-pyridyl)pyridazine molecule, four Cl atoms and nine water molecules. The two Ni atoms are octahedrally coordinated by N and Cl atoms, and by water molecules, and the three six-membered rings, a pyridazine and two picolines, are planar to within 0.181 (3) Å. The crystal structure is stabilized by an intra- and intermolecular hydrogen-bonding scheme involving water–water and water–chlorine interactions.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1107/S0108270100010507
Permalink