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  • 11
    ISSN: 0268-2605
    Keywords: siloxanes ; carbohydrate modified ; surfactants ; saccharide ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New siloxanyl-modified carbohydrate surfactants of the amide and glycoside type have been synthesized by coupling between defined as well as higher-molecular-weight siloxanes and carbohydrate structures via spacers of different lengths and hydrophilic power. Linear and branched monohydrogen di-, tri-, tetra- and penta-siloxanes and polyhydrogen siloxanes as well as mono- and di-saccharide lactone structures have been found to be good starting materials for the synthesis of amides, often in quantitative yield, whereas glycosides had to be prepared in low-yield multistep sequences including protection/deprotection steps. Selected strategies were applied to polysiloxanes yielding quantitatively a broad variety of carbohydrate-modified comb-like structures. The new substances were characterized by means of 13C NMR spectroscopy, GC, capillary GC, GC-MS coupling and elemental analysis.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 12
    ISSN: 0268-2605
    Keywords: carbohydrate surfactants ; wetting behaviour ; siloxane ; silane ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The wetting behaviour of carbohydrate surfactants bearing siloxane, carbosilane, polysilane or silane moieties has been investigated. By static surface tension (γlv, σ) and wetting tension (γsv-γsl, α) measurements on a non-polar perfluorinated surface (FEP®), the contact angles of aqueous surfactant solutions above the critical micelle formation concentration (cmc) were determined. Surface tension and wetting tension react independently on defined changes in the chemical structure of the surfactant molecules. Siloxane surfactants reduce the surface tension most effectively, whereas for a neopentyl-substituted silane derivative the lowest solid/liquid interfacial tension was found. The data for isomeric siloxanes, carbosilanes and silanes suggest that donor-acceptor forces at solid interfaces have a maximum range of about 4.5 Å. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 870-871 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1427-1432 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method of evalution of the effect of electron beam on the latent changes in degrading polymer resists has been developed on the base of measurement of the developing curve under an interference microscope. An evalution procedure using the unit parameters (film thickness and development time) has been suggested for the characterization of the sensitivity and contrast of resists.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 1483-1490 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The sizes of dissolved polymers can be estimated a priori at infinite dilution and under theta conditions from existing theories. The effects of concentration can be calculated by assuming that the hydrodynamic volume decreases from a maximum value at infinite dilution toward the theta condition volume, which is reached when the volume fraction of solvated polymer in solution is unity. The predicted hydrodynamic volumes coincide with results of small-angle x-ray scattering and effects of solvent and concentration on gel permeation chromatography elution volumes.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 16
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Lipotrophin (62-77) or Ac-gastrin releasing peptide was incubated with immobilized carboxypeptidase Y or aminopeptidase M. Subsequent aliquots of each incubation mixture were analysed by fast atom bombardment mass spectrometry using a dithiothreitol/dithioerythritol liquid matrix. The use of immobilized enzymes and volatile buffers for exopeptidase digestions enabled rapid and facile separation of enzyme from digestion products. This approach to mass spectral peptide analysis reduced spectral background arising from a glycerol matrix, buffer salts, or enzyme proteins and contaminants, enabling analysis of as little as 200 picomoles of a suitable peptide.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 17
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Proton NMR. spectra of purine, adenine, guanine and methylsubstituted guanines have been measured in CF3COOH, FSO3H and FSO3H—SbF5—SO2 at 27° and low temperatures. These conditions permit to study multiple protonation of purines, using chemical shifts of CH, NH and OH protons. The spectra of mono-, di- and tri-cations are described and fully assigned.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 18
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Proton-NMR. spectra of amino- and hydroxypyrimidines including biologically important bases have been measured in four solvents: CF3COOH, CF3COOH—SO2, FSO3H and FSO3H—SbF5-SO2 at 27° and -55°C. In CF3COOH mono-cations are formed, whereas in FSO3H and FSO3H—SbF5-SO2 double protonation occurs. In each case the structures of the protonated species are derived from the chemical shifts of CH, NH and OH protons and proton-proton spin coupling constants. A combination of the measurements described leads to a complete assignment of all proton resonances of the protonated pyrimidines. This approach is also recommended for the structural determination of heterocyclic compounds.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 291-310 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The wire-coating process was analyzed numerically making use of a particular die design employed in highspeed industrial operations. Both the lubrication approximation theory and a fully two-dimensional finite element analysis were applied under isothermal and nonisothermal conditions, respectively. Particular emphasis has been given to the heat transfer effects between the melt arid the solid and free boundaries. A variety of thermal boundary conditions was studied, ranging from adiabatic to constant temperature walls. The influence of dimension less groups such as Peclet, Nahme, and Biot numbers is examined. Oscillation-free solutions are obtained for the temperature field by using a standard finite element Streamline-Upwind/Petrov-Galerkin technique. Rheological data for a wire-coating low-density polyethylene (LDPE) resin (Alathon-3535) were used in the analysis. The predictions include pressure and temperature distributions, shear stresses and shear rates both at the die wall and the wire, and wire tension for different wire speeds. The numerical results are compared with a set of experimental data for LDPE in a typical die used by Du Pont Co. It is found that the isothermal lubrication approximation for power-law fluids overestimates pressure distributions when applied at die operating temperature. The nonisothermal finite element analysis gives better predictions, especially when realistic thermal boundary conditions are imposed, with the experimental results lying between those found from simulations assuming isothermal walls (upper limit) and adiabatic walls (lower limit).
    Additional Material: 26 Ill.
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 49 (1850), S. 191-192 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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