ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The various modes of fragmentation of 1,3-dithiolane and 1,3-oxathiolane under electron-impact have been discussed on the basis of the variation of their mass spectra with electron energy, the high resolution analysis and the AP's of the main ions. They are shown to be similar in both compounds, but considerably different from those of 1,3 dioxolane. From the AP of the [C2H5S]+ ion in 1,3-dithiolane, a heat of formation of 63 kcal/mol for the free radical CHS is obtained.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210060407
Permalink