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  • 11
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. Using angle-dependent photoemission spectra of core and valence levels we show that metallic, single crystal K3C60 is terminated by an insulating or weakly-conducting surface layer. We attribute this to the effects of strong intermolecular correlations combined with the average surface charge state. Several controversies on the electronic structure are thereby resolved.
    Type of Medium: Electronic Resource
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  • 12
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In a high resolution48Ca(d,3He) experiment at 80 MeV evidence has been found for a 7/2− state at 1.97 MeV in47K with a spectroscopic factor of C2S=0.08 corresponding to a ~4% admixture of πf2(s,d)−2 configurations in the ground state of Ca.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of intelligent manufacturing 2 (1991), S. 261-268 
    ISSN: 1572-8145
    Keywords: AI ; neural networks ; expert system ; process control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract This paper presents an architecture which combines artificial neural networks (ANNs) and an expert system (ES) into a hybrid, self-improving artificial intelligence (AI) system. The purpose of this project is to explore methods of combining multiple AI technologies into a hybrid intelligent diagnostic and advisory system. ANNs and ESs have different strengths and weaknesses, which can be exploited in such a way that they are complementary to each other: strengths in one system make up for weaknesses in the other, andvice versa. There is, presently, considerable interest in ways to exploit the strengths of these methodologies to produce an intelligent system which is more robust and flexible than one using either technology alone. Any process which involves both data-driven (bottom-up) and concept-driven (top-down) processing is especially well suited to displaying the capabilities of such a hybrid system. The system can take an incoming pattern of signals, as from various points in an automated manufacturing process, and make intelligent process control decisions on the basis of the pattern as preprocessed by the ANNs, with rule-based heuristic help or corroboration from the ES. Patterns of data from the environment which can be classified by either the ES or a human consultant can result in a high-level ANN being created and trained to recognize that pattern on future occurrences. In subsequent cases in which the ANN and the ES fail to agree on a decision concerning the environmental situation, the system can resolve those differences and retrain the networks and/or modify the models of the environment stored in the ES. Work on a hybrid system for perception in machine vision has been funded initially by an Oak Ridge National Laboratory seed grant, and most of the system components are operating presently in a parallel distributed computer environment.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 73-79 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Perturbation chromatography previously has been used experimentally as an efficient method for obtaining sorption equilibria for systems with up to two vapor phase components at finite concentration. The objective of this work was to obtain a theoretical result that could be used for experimental determinations of sorption of multiple interfering species at finite concentration. Results obtained are applicable for both non-stoichiometric and stoichiometric situations for systems that may have flowing phase velocity and volume changes associated with interphase transport and also may have interactions among the sorbed components. The dependence of each effluent peak characteristic velocity upon all of the component equilibrium isotherms requires that the equilibria be considered as a whole by simultaneously fitting a set of composition grid perturbation response data to appropriate isotherm surface equations.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1948-1953 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Elution times determined from perturbation chromatography experiments are functions of all sorbing species isotherms through the concentration partial derivatives. Measurements at a sufficient number of appropriate compositions along with isotherm models and adjustable parameters allow reduction of the retention time data to VLE by a nonlinear parameter estimation procedure described in this paper. The method can be implemented for both empirical isotherm models, which can be used to minimize model deficiencies, and for theoretical thermodynamic models, which have extrapolation potential and may require fewer parameters.
    Type of Medium: Electronic Resource
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  • 16
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work brings together recent gas chromatography experiments and theory involving multiple sorbing species at finite concentration, and theories for multicomponent polymer solutions by means of the parameter estimation procedure of Part 1. Results quantitatively describe the wide variation in peak retention times that are caused by phase equilibrium and chromatographic interference, the best solution models doing so to within or near experimental error. The chromatographic method is capable of detecting differences and peculiarities in the various polymer solution models in both the accuracy of the calculated retention times and the sensitivities of the calculations to the model parameters. Perturbation chromatography offers some unique capabilities for multicomponent vapor-liquid equilibrium determinations.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1069-1076 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidation of asphalt is a major cause of pavement failure. The low-temperature oxidation kinetics of 14 asphalts are presented. At constant temperature and oxygen presure, asphalt oxidation occurs in two stages: (1) a relatively rapid-rate period, followed by (2) a long period of constant rate. Activation energies for the constant-rate region vary from 64 to 109 kJ/mol, and reaction orders relative to oxygen pressure vary from 0.25 to 0.61. This variation in activation energy and reaction order leads to skepticism regarding the present practices of evaluating road-condition asphalt-hardening rates at a single elevated temperature and perhaps at an elevated pressure. The asphalts occur in essentially two groups, one at high values of both activation energy and reaction order and the other at low values of each. The data indicate the existence of an isokinetic temperature near 100°C. The degree of oxidation that occurs during the initial rapid-rate region varies inversely with the oxygen reaction order of the constant-rate region.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 3 (1965), S. 27-29 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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