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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 120 (1995), S. 159-169 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Glass inclusions in olivine and diopside phenocrysts from pyroclasts of various eruptions of Vesuvius are representative of the magmas that supplied the volcano in the last 4–5000 years. During this interval the volcano alternated between open conduit activity (e.g. 1944 and 1906 eruptions) with long pauses interupted by Plinian and sub-Plinian eruptions (e.g. 3360 B.P. “Avellino”, A.D. 79 “Pompei”, A.D. 472 “Pollena”). The eruptive behaviour was conditioned in all cases by the presence of shallow reservoirs: two cases are distinguished: (1) small and very shallow, 1906-type; (2) large and deeper Plinian-sub-Plinian magma chamber. Lapilli of 1906 lava fountains contain olivine (Fo89.5–90.4) including Cr-spinel [Cr/(Cr+Al)] (Cr#〉75) and volatile-K-rich tephritic glasses, which represent the first recognized Vesuvius primary magmas. Mg-poorer olivine (Fo83–89) also occurs in 1906 and 1944 products; it formed within the shallow reservoir, together with pyroxene and leucite, between 1200 and 1130°C, from K-tephritic melts (MgO=6–8 wt%). The Plinian and sub-Plinian pumices contain diopside, phlogopite and minor olivine (Fo85–87) representing adcumulates wrenched from the chamber walls. Glass inclusions in diopside (and some olivine) range from K-basalt to K-tephrite (MgO=6–8 wt%), with homogenization temperature of 1130–1170°C. They have been regarded as representative of the magmas supplying the Plinian-sub-Plinian chamber(s). The Avellino glass inclusions have K-basaltic compositions, contrasting with the mostly K-tephritic Pompei and Pollena inclusions. They display lower C1 and P contents with respect to the younger tephritic melts, and these variations should reflect primary features of the mantle-derived magmas. The primary and the near-primary Vesuvius magmas, as illustrated by melt inclusions, emphasize high K, P and volatile (H2O, Cl, F, S) contents, with high K2O/H2O (2–2.5), Cl/F (2.5) and Cl/S (2–3) ratios, consistent with a metasomatized mantle source, and distinguishing the Vesuvius potassic primary magmas from those of the northern part of the Roman Province.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 120 (1995), S. 186-196 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The origin and the relationships between the high potassic (HKS) and potassic (KS) suites of the Roman Comagmatic Province and the nature of their primary magmas have been intensively debated over the past 35 years. We have addressed these problems by a study of mineralogy (olivine Fo92-87, Cr-spinel and diopside) and melt inclusions in olivine phenocrysts from a scoria sample of Montefiascone (Vulsini area). This rock is considered as one of the most primitive (MgO=13.5 wt%, NiO=340 ppm; Cr=1275 ppm) in the northern part of the Roman Comagmatic Province. The compositions of both the olivine and their melt inclusions are controlled by two main processes. In the case of the olivine Fo〈90.5, fractional crystallization (olivine+diopside+minor spinel) was the principal mechanism of the magma evolution. The olivine (Fo92-90.5) and the Cr-spinel (Cr?= 100. Cr/(Cr+Al)=63–73) represent a near-primary liquidus assemblage and indicate the mantle origin of their parental magmas. The compositions of melt inclusions in these olivine phenocrysts correspond to those of poorly fractionated H2O-rich (∼1 wt%) primary melts (MgO=8.4–9.7 wt%, FeOtotal=6–7.5 wt%). They evidence a wide compositional range (in wt%: SiO2=46.5–50, K2O=5.3–2.8, P2O5=0.4–0.2, S=0.26–0.12; Cl=0.05–0.03, and CaO/Al2O3= 0.8–1.15), with negative correlations between SiO2 and K2O, Al2O3 and CaO, as well as positive correlations between K2O, and P2O5, S, Cl, with nearly constant ratios between these elements. These results are discussed in terms of segregation of various mantle-derived melts. The high and constant Mg? [100. Mg/(Mg+Fe2+)] 73–75 of studied melts and their variable Si, K, P, Ca, Al, S contents could be explained by the melting of a refractory lithospheric mantle source, heterogeneously enriched in phlogopite and clinopyroxene (veined mantle source).
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 157 (1992), S. 273-280 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A review of the nuclear reactions used to determine fluorine is presented. In order to optimize the detection of fluorine in biological or in geological samples, a comparison of the performances obtained with the three nuclear reactions19F(p, α0)16O,19F(p, αγ)16O,19F(p, p'γ)19F was made. The last reaction was chosen for its sensitivity. The homogeneity of biological and geological standard samples, the linearity of the calibration curves, and the stability of fluorine under the beam were tested.
    Type of Medium: Electronic Resource
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