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  • 1
    Digitale Medien
    Digitale Medien
    Kinetic studies of Fischer-Tropsch synthesis on suspended iron/potassium catalyst - rate inhibition by carbon dioxide and water (1986)
    s.l. : American Chemical Society
    Industrial and engineering chemistry 25 (1986), S. 643-649 
    Details
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1021/i200034a008
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Photochlorination of tetrachloroethene in carbon tetrachloride solutions (1993)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 6 (1993), S. 545-550 
    Details
    ISSN: 0894-3230
    Schlagwort(e): Organic Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Validation of the mechanism of tetrachloroethene photochlorination at low C2Cl4 concentrations was investigated. The reaction was examined in carbon tetrachloride solution. For initial tetrachloroethene concentrations below 2 mol I-1, the solvent participates in a free-radical chain photochlorination. The presence of CCl4 disturbs the course of this particular chain reaction and influences the duration of the induction period.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/poc.610061003
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    A kinetic study of benzoyl peroxide decomposition in graft copolymerization bath (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 3177-3183 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The rates of decomposition of benzoyl peroxide have been studied in water alone and in the presence of the components of graft copolymerization bath, viz. diphenyl and acrylic acid, in the temperature range of 363-403 K. Kinetic parameters such as reaction order for the peroxide, preexponential factor, and activation energy were evaluated from experimental data. The implication of these results to the initiation of graft copolymerization of acrylic acid onto polyester fabrics is discussed.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1989.070371109
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chemically induced graft copolymerization of acrylic acid onto polyester fabrics. I. Kinetic investigation of grafting (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 1241-1249 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The kinetics of grafting of acrylic acid onto poly(ethylene terephthalate) fabrics initiated by benzoyl peroxide has been studied. Extent of grafting depended upon time, concentration of the initiator and the monomer, as well as the presence of the activator used. From the temperature dependence of the initial rate of grafting the overall activation energy for grafting was found to be 90 kJ/mol. The results of the monomer and temperature dependence found in this study are consistent with the rate expression derived from a normal kinetic scheme for grafting.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1988.070350510
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Kinetics of benzene photochlorination (1983)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 15 (1983), S. 119-128 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An empirical approach to the kinetic investigations of photo-initiated liquid-phase chlorination of benzene is presented. Reaction order and the reaction constants for chlorine consumption and for the production of hexachlorocyclohexane isomers were evaluated from experimental data.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550150203
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Kinetics of tetrachloroethylene photochlorination (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 345-352 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Photochlorination of tetrachloroethylene has been studied in a homogeneous liquid system. Kinetic parameters such as reaction orders for chlorine, tetracholoroethylene and light intensity, preexponential factor, and activation energy were evaluated from experimental data. The following kinetic equation was obtained by parameter estimation following the Marquardt procedure: \documentclass{article}\pagestyle{empty}\begin{document}$$ r = \left( {4.02 \pm 0.46} \right)10^{ - 5} \exp \left( { - \frac{{54,700 \pm 200}}{{RT}}} \right)I^{0.489 \pm 0.003} C_{Cl_2 }^{0.889 \pm 0.160} C_{C_2 Cl_4 }^{1.040 \pm 0.042} $$\end{document}
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550160405
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