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  • 1
    Electronic Resource
    Electronic Resource
    Quadrupole echoes and the 127I nuclear hexadecapole interaction in KI (1991)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 4796-4801 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A quadrupole echo method for searching for the nuclear hexadecapole interaction (HDI) is described. A sequence of three radio frequency pulses applied at times 0, τ, and nτ (n〉1) gives a simple pattern of nuclear spin (5)/(2) echoes when only the nuclear Zeeman and quadrupole interactions are present. Calculations for n=2.5, 3.0, 4.0, and 5.0 show that these patterns undergo an elaborate change when the HDI is also present and that these echo patterns are unique to the HDI. Three pulse echoes were used to search for the 127I HDI in a single crystal of KI but, for this sample, a two pulse sequence was found to be more effective. For KI, 2.8 kHz is the estimated magnitude of the 127I hexadecapole coupling constant, eHV(4)/h, where eH is the 127I electric hexadecapole moment and V(4) is a fourth derivative of the electrostatic potential at the nuclear site. This is the smallest HDI measured in a solid so far.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.461723
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  • 2
    Electronic Resource
    Electronic Resource
    Proton shielding of the oxonium ion in perchloric acid monohydrate (1990)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 2959-2960 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.458882
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  • 3
    Electronic Resource
    Electronic Resource
    Proton chemical shifts in some hydrogen bonded solids and a correlation with bond lengths (1989)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 7387-7391 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using multipulse techniques, principal values of the proton nuclear magnetic resonance (NMR) chemical shift tensors were measured at room temperature for the monoclinic form of oxalic acid, potassium hydrogen oxalate, and potassium hydroxide. The isotropic and perpendicular shifts of the first two compounds, which are of medium hydrogen bond strength, were found to fit the linear correlation with O⋅⋅⋅O distance, RO⋅O, established by Rohlfing, Allen, and Ditchfield for medium and strongly O–H⋅⋅⋅O hydrogen bonded solids. Although KOH is very weakly hydrogen bonded, the shifts were also found to conform to the correlation, at least as well as does the other data, thus extending this to weakly hydrogen bonded solids. An empirical correlation of the isotropic and perpendicular shifts with exp(−RO⋅O/ρ), where RO⋅O is in A(ring) and ρ is 0.94 A(ring), is given here which has better agreement with the data and has an interpretation in terms of a simple ionic model of an O–H⋅⋅⋅O bond.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.457262
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  • 4
    Electronic Resource
    Electronic Resource
    1H shielding anisotropy in Mg(OH)2: The isolated OH− group (1988)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 2284-2288 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The proton NMR shielding tensor was measured at room temperature in the hexagonal layered compound magnesium hydroxide. The isotropic shielding is 29.9±2 and the anisotropy is 12.7±2 ppm, on the 1H absolute scale. From a Gierke and Flygare (GF) analysis of the data the OH− spin–rotation constant was found to be 51±14 kHz. The GF contributions from the neighbors of a given OH− group were subtracted from the experimental shielding and corrections were made for the effects of vibrational motion to give an isotropic shielding of 29.9±2, with an anisotropy of 13.7±2 ppm, for an isolated OH−. The OH− shielding anisotropy is in good agreement with the ab initio calculations of Ratcliffe et al., but the isotropic shielding is not. Proton spin–lattice relaxation measurements at 300 and 77 K gave evidence of proton conductivity in Mg(OH)2.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.454062
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  • 5
    Electronic Resource
    Electronic Resource
    Metastasizing leiomyoma of the uterus and hormonal manipulations. Case report (1986)
    Oxford, UK : Blackwell Publishing Ltd
    BJOG 93 (1986), S. 0 
    Details
    ISSN: 1471-0528
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1471-0528.1986.tb08043.x
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  • 6
    Electronic Resource
    Electronic Resource
    BEHAVIORAL RESPONSE OF FOUR SPECIES OF BALAENOPTERID WHALES TO BIOPSY SAMPLING (1999)
    Oxford, UK : Blackwell Publishing Ltd
    Marine mammal science 15 (1999), S. 0 
    Details
    ISSN: 1748-7692
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: Behavioral responses to biopsy sampling of four species of northwestern Atlantic balaenopterid whales summering in the estuary and Gulf of St. Lawrence, Quebec, from 1990 to 1995 were studied to determine if this technique was an important disturbance to the whales. A total of 447 biopsy samples were taken using a small punch-type biopsy tip fired from a crossbow. Biopsies were successfully taken from 91.2% of the whales approached. Whales displayed no reaction to 45.2% of the successful biopsy attempts. Whales that responded to biopsy sampling typically resumed their normal behavior immediately or within a few minutes. Most humpback whales displayed a hard tail flick, and the majority of fin and blue whales submerged following biopsy sampling. Significantly different frequencies and intensities of responses were found between whale species. Minke and humpback whales were found to be more sensitive to biopsy sampling than fin and blue whales. Response frequencies were similar between females and males for all species, with the exception of fin whales where females had a higher response frequency than males. Biopsy sample length, i. e., penetration depth, did not explain variations in response intensity but may influence response frequency to biopsy sampling. Group size, geographical region, and number of biopsies taken per whale were not factors that explained variation in behavioral responses. The biopsy technique was found to be an efficient method for obtaining high-quality whale skin and blubber samples with limited behavioral disturbance to balaenopterid whales.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1748-7692.1999.tb00783.x
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  • 7
    Electronic Resource
    Electronic Resource
    115In hexadecapole interaction upper limit in InP: 31P–115In exchange and pseudodipolar coupling constants (1994)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 4708-4709 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using NMR multipulse methods an upper limit of 20 kHz was established for the 115In hexadecapole coupling constant in InP. From the orientation dependence of the 31P second moment the magnitude of the 31P–115In exchange coupling constant and the pseudodipolar coupling constant were obtained. The results are 0.17±0.04 kHz, and −0.30±0.07 or −0.99±0.07 kHz, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.466258
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  • 8
    Electronic Resource
    Electronic Resource
    Improvements to a commercial constant pressure high speed liquid chromatograph (1973)
    s.l. : American Chemical Society
    Analytical chemistry 45 (1973), S. 1001-1002 
    Details
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ac60328a020
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  • 9
    Electronic Resource
    Electronic Resource
    19F shielding anisotropy in RbCaF3 (1987)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 68-72 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A 19F NMR multipulse measurement of the chemical shift in a single crystal of cubic RbCaF3 gave −47.0±3 ppm as the isotropic value with respect to C6F6, and 128.7±6 ppm as the anisotropy. The shielding is accounted for by the usual diamagnetic and paramagnetic ionic overlap and covalent terms. As a result, the Ca++ −F− bond is estimated to be 98% ionic. No significant spectral changes were found when the crystal was cooled below the cubic to tetragonal phase transition temperature. Reasons for this are given.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.453565
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  • 10
    Electronic Resource
    Electronic Resource
    19F shielding anisotropy in KMgF3 (1988)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 1468-1469 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.454220
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