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  • 1
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Aligned carbon nanotubes were synthesized on Ni-coated Si substrates using microwave plasma-enhanced chemical vapor deposition. The surface morphology of Ni thin films was varied with the rf power density during the rf magnetron sputtering process. It was found that the growth of carbon nanotubes was strongly influenced by the surface morphology of Ni thin film. Pure carbon nanotubes were synthesized on Ni thin film with uniformly distributed grain sizes, whereas large amounts of carbonaceous particles were produced in addition to the nanotubes, when the nanotubes were grown on Ni thin film with widely distributed grain sizes. With decreasing Ni-grain size, the diameter of nanotubes decreased and the length increased. High-resolution transmission electron microscope images clearly demonstrated the nanotubes to be multiwalled, and the graphitized structures were confirmed from the Raman spectra. Efficient field emission was observed from the diode structure with the nanotube tips. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2212-2214 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We systematically analyze the stress-strain-temperature relationships and include thermal strain contributions to the misfit-strain only formalism of strained-layer heterostructures. Application of this theory to the GexSi1−x/Si (100) and InxGa1−xAs/GaAs (100) system demonstrates that the thermal effect lowers the critical layer thickness significantly on both systems, in excellent agreement with experimentally measured values. Empirical formulae of the critical layer thickness in terms of a mole fraction and temperature for these systems are provided. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 5628-5632 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: An optical Kerr effect, which is the transient electric birefringence of isotropic molecular fluids when the molecules align themselves with external field, is investigated. Calculations have been carried out on the rotational diffusion of rod-like molecules in the presence of an arbitrary field strength. We will provide an exact recurrence relation with nonlinear effects and this recurrence relation is solved numerically to see how the nonlinearity affects the answer for various field strengths.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 81 (2002), S. 184-184 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 2877-2879 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We perform density-functional calculations to search for hydrogen adsorption sites and predict maximum storage capacity in single-walled carbon nanotubes. We find two chemisorption sites at top sites of the exterior and the interior of the tube wall. We further find that a form of H2 molecule can exist in an empty space inside nanotubes. The storage capacity of hydrogen in an empty space increases linearly with tube diameter. The maximum storage capacity is limited by the repulsive energies between H2 molecules inside nanotubes and those between H2 molecules and the tube wall. We predict that hydrogen storage capacity in (10,10) nanotube can exceed 14 wt % (160 kg H2/m3). © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 2367-2369 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Vertically aligned carbon nanotubes were synthesized on Ni-deposited Si substrates using microwave plasma-enhanced chemical vapor deposition. The grain size of Ni thin films varied with the rf power density during the rf magnetron sputtering process. We found that the diameter, growth rate, and density of carbon nanotubes could be controlled systematically by the grain size of Ni thin films. With decreasing the grain size of Ni thin films, the diameter of the nanotubes decreased, whereas the growth rate and density increased. High-resolution transmission electron microscope images clearly demonstrated synthesized nanotubes to be multiwalled. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 277-279 (Jan. 2005), p. 450-454 
    ISSN: 1013-9826
    Quelle: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Thema: Maschinenbau
    Notizen: Biodegradable superabsorbents, hydrolyzed AN(acrylonitrile)-grafted-SA(sodium alginate) copolymers were prepared in this study by graft copolymerization of acrylonitrile on sodium alginate and the subsequent hydrolysis of the resulting grafted copolymer. The absorbency was found to significantly depend on the % add-on, graft copolymerization conditions and hydrolysis conditions. The optimum condition for graft copolymerization to obtain the maximum % add-on (64.5%) was 4g SA, 12g AN, and 8.42g H2O2 in 100ml water at 70 oC for 10hr., respectively. The optimum hydrolysis conditions for the graft copolymer (64.5 % add-on) to reach the maximum water absorbency (2518g/g), saline absorbency (1558g/g), and WRV (288g/g) is 1g graft copolymer in 10 ml aqueous NaOH (1.0N) at 110 oC for 1 hr. Furthermore, this hydrolyzed AN-graft-SA showed agood biodegradability in enzymatic hydrolysis tests when compared with commercial superabsorbent materials
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    s.l. ; Stafa-Zurich, Switzerland
    Solid state phenomena Vol. 124-126 (June 2007), p. 1809-1812 
    ISSN: 1662-9779
    Quelle: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Thema: Physik
    Notizen: ZSM-5 was modified by alkaline and acidic solution to introduce mesoporosityin the crystals. Heterogenized Co(III) salen was prepared in the mesopores of ZSM-5 by‘ship-in-a-bottle’ method. Phenolic ring opening of epoxides was performed successfullyby using encapsulated chiral salen catalysts. Very high enantioselectivity and conversionwere obtained in PKR reaction by immobilized catalysts
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    International journal of biometeorology 37 (1993), S. 36-41 
    ISSN: 1432-1254
    Schlagwort(e): Seasonality ; Clothing ; Rectal temperature ; Skin temperature ; Thermal sensation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Abstract Thermoregulatory responses at ambient temperatures of 20 and 10° C in six male subjects wearing two different kinds of clothing were compared between summer and winter. The two different kinds of clothing were one insulating the upper half of the body lightly and the lower half of the body heavily (clothing A, the weight in the upper and lower halves of the body being, respectively, 489 g and 1278 g) and the other insulating the upper half of the body heavily and the lower half of the body lightly (clothing B: 1212 g and 559 g). The major findings are summarized as follow. (i) Rectal temperature was kept significantly higher in clothing B than in clothing A both in summer and winter. (ii) The fall of rectal temperature was significantly greater in summer than in winter in both types of clothing. (iii) Mean skin temperatures and skin temperatures in the face, chest, thigh and leg were significantly lower atT a of 10° C in summer than in winter in clothing A, while skin temperatures in the face and thigh were also significantly lower atT a of 10° C in summer than in winter in clothing B. (iv) Metabolic heat production was higher in summer than in winter at 20 and 10° C in both types of clothing. (v) The subjects felt cooler and colder toT a of 10° C in summer than in winter in both types of clothing. These different responses occurring between summer and winter are discussed mainly in terms of total conductance and dry heat loss.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Catalysis letters 57 (1999), S. 209-215 
    ISSN: 1572-879X
    Schlagwort(e): 1-butene ; skeletal isomerization ; mesoporous material ; acid site concentration ; monomolecular reaction
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract On the skeletal isomerization of 1-butene, mesoporous materials with mesopores too large to expect any shape selectivity have been used in order to investigate the effects of the concentration of acid sites on the conversion of 1-butene and the selectivity for isobutene. The concentrations of acid sites can be varied through the control of the Si/Al ratio. The conversion of 1-butene increases with increasing the aluminium content of mesoporous materials, while the selectivity for isobutene decreases. The results of ammonia TPD, IR measurement of 1-butene adsorption, and TG analysis of used catalysts indicate that distant location of activated 1-butene molecules induces the monomolecular reaction over the mesoporous materials with low aluminium content, resulting in high selectivity for skeletal isomerization. On the mesoporous material with high aluminium content, however, the high concentration of activated 1-butene molecules accelerates the multimolecular oligomerization and, thus, reduces the selectivity.
    Materialart: Digitale Medien
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