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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 1461-1472 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Field desorption mass spectrometry (FDMS) was applied to the study of the initiation mechanism of thermal polymerization of styrenes. The FD mass spectrum was measured for a cooligomer of α,α,β-trideuterostyrene and p-methoxystyrene produced by thermal polymerization using ethylbenzene as a solvent, and this was compared with the spectrum of an oligomer of p-methoxystyrene. The above two FD mass spectra showed characteristic differences, depending upon the number of hydrogen and deuterium atoms and upon the presence or absence of the methoxy group, in the oligomers. Molecular species observed in the spectra were identified based on these considerations. As a result, we could distinguish the “true trimer” produced from three monomers from the “cross trimer” produced from fragments of five monomers. It was found that the “true trimer” was the major constituent in the trimer region, and that the “true trimer” was produced mainly by the cage reaction between initiating radicals.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 297-304 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The advancing contact angle of water on plastic film coatings on metal was measured against both the air and the metal side surfaces after their being peeled off from the metal substrate. The plastic used was a methacrylate copolymer, and it was baked on cadmium, aluminum, nickel, iron, and gold. Contact angle for the air side was about 74° at 25°C. for all metals, but the values on the metal side differed considerably, ranging from 76° for gold to 50° for cadmium. At the same time the static breaking strengths of the same films were investigated by applying a knife-edge vertically to the film with increasing load and measuring the weight at which the electric resistance through the film became zero. Increasing film thickness gave increasing strength, but further thickening made the film weaker with a tendency for crack formation. The film-metal combinations of larger contact angle difference generally also showed the higher breaking strength.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 2303-2316 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Field desorption mass spectra of normal and deuterated styrene oligomers synthesized in several alkylbenzenes were measured. Analysis of the mechanism of thermal oligomerization was carried out by identifying the molecular species in the reaction system using field desorption mass spectra. As a result, the existence of several kinds of molecular species was confirmed. The minor molecular species originated from dissolved oxygen, from the cleavage of solvent radicals to which oxygen was attached, or from H-D exchange in the oligomerization of deuterated styrene. The major molecular species originated from radical telomerization of solvents and styrene dimers, from the recombination termination reaction, and from the cage reaction between initiating radicals. Field desorption mass spectrometry was found to be useful for analyzing the mechanism of styrene oligomerization as well as characterizing the oligomers.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 18 (1987), S. 153-155 
    ISSN: 0377-0486
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The Raman optical activity (ROA) spectra of some azo dyes binding to cyclodextrins have been measured. This appears to be the first successful attempt to measure the ROA induced in achiral molecules by intermolecular interaction with chiral molecules. There was no relationship between the ROA signals and the Raman shifts accompanying inclusion phenomenon. From comparison of the ROA spectra of methyl orange with α-cyclodextrin and congo red with γ-cyclodextrin, it seems that the ROA spectra reflect the difference in the positions of the SO3- groups in the guest molecules.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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