ISSN:
0360-6376
Schlagwort(e):
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The influence of the reaction medium on the polycondensation of the tetranitriles of tetracarboxylic acids and diamines has been investigated. The reaction in phenol and cresols yields polymers with macroheterocycles in the chain - polyhexasocyclanes. If phenols with electron-accepting substituents are used as reaction medium, nonmacrocyclic polymers with side aroxyl groups in the chain, polyisoindoxazenes - are formed. The properties of these polymers were studied. Macroheterocyclic compounds formed by condensation of phthalodinitrile with diamines can be used as one of the initial substances in polyhexasocyclane synthesis. Polyamidohexasocyclanes were prepared by polycondensation of macroheterocycles with dicarboxylic acid dichlorides. Some regularities of their formation and their properties were investigated.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pol.1984.170220505
Permalink