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  • Digitale Medien  (19)
  • Polymer and Materials Science  (19)
  • 1
    Digitale Medien
    Digitale Medien
    Thermal properties of some fully aromatic thermotropic liquid crystal polyesters (1990)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 75-87 
    Details
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Wholly aromatic liquid crystalline main chain polyesters derived from terephthalic acid, phenyl- or (1-phenylethyl)hydroquinone modified with either 3,4′- or 4,4′-dicarboxydiphenylether and p-hydroxybenzoic acid, have been prepared by acidolysis and thermally investigated. All prepared polyesters exhibit excellent thermal stability up to about 400°C, however, the (1-phenylethyl)hydroquinone polyesters generally showed lower stability. Melting points could be decreased to around 200°C without any decrease in the thermal stability or the nematic range.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1990.080280106
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  • 2
    Digitale Medien
    Digitale Medien
    Microanalysis of polymers using a windowless energy-dispersive X-ray detector (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 201-206 
    Details
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The surface compositions of various polymeric films, grown electrochemically on platinum foils, have been investigated by energy-dispersive x-ray analysis in conjunction with scanning electron microscopy (SEM/EDS). Comparison of the relative area ratios of peaks for the C and N Kemission lines show that the EDS may be used to study the surface composition of polymers. The evidence presented strongly suggests that there is limited structural degradation and the elemental composition is not changed under the electron beam at relatively low accelerating voltages. This technique statistically samples the repeat units of the polymer. For samples grown in both aqueous and nonaqueous solutions. SEM/EDS provides evidence for extensive contamination with oxygen.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1988.080260120
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  • 3
    Digitale Medien
    Digitale Medien
    Preparation and testing of local polyester composites based on unsaturated polyesters as binder (1986)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 31 (1986), S. 2705-2710 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A series of polymeric composites were prepared with sand/polyester ratio 92:8%. The sand used was local one. The polymeric composites were tested for their compressive strength, exterior volume, porosity, water uptake, specific gravity, volume of open pores and bulk density. The mechanical properties of these polymeric composites were within the range required for building bricks. No significant differences were observed between the polymeric composites made of glass sand and those from untreated sand except in exterior volume and compressive strength. Medium untreated sand was found to give better results in the mechanical properties.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1986.070310825
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  • 4
    Digitale Medien
    Digitale Medien
    Structure and properties of p-carboxysuccinanilic polyester resins (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 75-83 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Polyester resins were prepared by the reaction of p-carboxysuccinanilic acid ethyl ester with ethylene glycol and 1,4-butenediol. Also, unsaturated polyester resins were prepared by the copolymerization of p-carboxysuccinanilic acid ethyl ester and maleic anhydride with ethylene glycol, 1,6-hexanediol, 1,4-butenediol, and 2-butyne-1,4-diol. All the polyester resins and the copolyesters have been characterized and were found to cure with styrene, except those prepared in the absence of maleic anhydride. The properties of the cured products in the form of films were determined. Infrared and nuclear magnetic resonance (NMR) spectroscopy were used for both qualitative and quantitative analyses of the polyester resins and their hydrolyzate products after curing with styrene.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1988.070350107
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  • 5
    Digitale Medien
    Digitale Medien
    Preparation by suspension polymerization of porous beads for enzyme immobilization (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 39 (1990), S. 169-177 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Porous beads have been prepared by suspension polymerization of acrylic monomers and divinyl benzene in the presence of a porogen. The porosity varies greatly with the polymer composition, with the amount and type of porogen and with the conditions for the preparation. The enzyme binding capacity and activity has been determined for a lipase. The best results are found for crosslinked poly(methyl methacrylate) beads while other polyacrylates are less effective. Compositions based on poly(methacrylic acid) are not suitable for enzyme binding.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1990.070390114
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  • 6
    Digitale Medien
    Digitale Medien
    Synthesis, crosslinking and degradation of some unsaturated polyester resins (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 1117-1124 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Some unsaturated polyester resins were prepared by the ester interchange between p-carbethoxymaleananilic acid and p-carbethoxysuccinanilic acid with saturated and unsaturated diols. Moreover, copolymers were also synthesized by the polyesterification of the aforementioned acids and maleic anhydride with the above-mentioned glycols. The structure of both the unsaturated polyester resins and copolymer resins was established by IR, UV, and NMR spectroscopy. Also, viscosity measurements and molecular weight determinations were further tools for their structural elucidation. All the products were attempted to cure with styrene in the presence of benzoyl peroxide as initiator, and the produced network structures, in the form of films, were tested as surface coating materials for glass and metals. The structure of the cured products was established after their degradation, by physical and spectroscopical means.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1987.070340320
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  • 7
    Digitale Medien
    Digitale Medien
    Abstract of the PhD thesis “Corrosion behaviour of stainless steels and nickel alloys in hot concentrated static and flowing sulphuric acid and flowing sulphuric acid” (1994)
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 45 (1994), S. 206-206 
    Details
    ISSN: 0947-5117
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/maco.19940450317
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  • 8
    Digitale Medien
    Digitale Medien
    The IRC in materials for high-performance applications (1995)
    Weinheim : Wiley-Blackwell
    Advanced Materials 7 (1995), S. 961-963 
    Details
    ISSN: 0935-9648
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/adma.19950071202
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  • 9
    Digitale Medien
    Digitale Medien
    Einsatz von Cross-flow-Techniken in der BioverfahrenstechnikVortrag von M. H. Kopf auf dem Jahrestreffen der Verfahrens-Ingenieure, 21. bis 23. Sept. 1988 in Hannover. (1989)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 61 (1989), S. 459-468 
    Details
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Use of cross-flow techniques in biotechnology. This progress report summarises experience and results gained during the development and optimisation of various micro- and ultrafiltration process. The major emphasis lies on the calculation of data which precede actual separation experiments and which define the separation or work-up problem and the product system involved. To this end the author presents a checklist covering the following areas: definition of the problem at hand, characterisation of the product system and demands placed on membrane plant and membranes. The second area of emphasis is the concept of a flexible membrane test plant. With the aid of this plant, all the data necessary for design and optimisation of a membrane process can be worked out during the laboratory experimentation phase. The principal process engineering tools available for optimisation of the specific filtration performance and maximisation of the product yield are considered. The report considers both the effects and the theoretical fundamentals of techniques for maintaining steady flow of filtrate and for avoiding nonspecific adsorption.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cite.330610607
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  • 10
    Digitale Medien
    Digitale Medien
    Direct observation of morphological differences as a function of reaction temperature in model systems for polyurethane foams (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 3065-3077 
    Details
    ISSN: 0887-6266
    Schlagwort(e): polyurethanes ; AFM ; atomic force microscopy ; phase separation ; crosslinking ; Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: A series of polyurea urethanes was isothermally synthesized from toluene diisocyanate (TDI), water, and trifunctional poly(propylene oxide) in the temperature range of 50-150°C. Morphologies of the samples vary significantly as a function of reaction temperature. In this system, phase separation competes with polymerization and crosslinking. Both transmission electron microscopy and atomic force microscopy have shown a network type of structure for the 50°C samples, while the 150°C samples appear to be homogeneous. Infrared analysis shows that samples prepared at 150°C possess a morphology that is less strongly hydrogen bonded and has a broader distribution of hydrogen-bonded states compared to those prepared at lower temperatures. From this combination of techniques, it can be inferred that phase separation occurs faster than crosslinking at low temperatures; consequently, a phase-separated morphology forms. In contrast, crosslinking occurs faster than phase separation at higher reaction temperatures. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 3065-3077, 1998
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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