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Die Hydrierung substituierter 1,1-Cyclopropandicarbonitrile (1984)

Neumann, Norbert ; Boldt, Peter

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 1935-1939

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: The Hydrogenation of Substituted 1,1-CyclopropanedicarbonitrilesOn catalytic hydrogenation of 2-butyl-, 2,2-dimethyl-, and 2,2,3-trimethyl-1,1-cyclopropane-dicarbonitrile (1 - 3) ring-opening at the C-1 - C-3 bond occurs as predicted by the rule of Musso et al.2). Two highly substituted cyclopropanes (10, 12) gave no hydrogenolytic ring fission.

Notes: Bei der katalytischen Hydrierung von 2-Butyl-, 2,2-Dimethyl- und 2,2,3-Trimethyl-1,1-cyclopropandicarbonitril (1 - 3) findet entsprechend der Regel von Musso et al. 2) Ringöffnung an der C-1 - C-3-Bindung statt. Zwei hochsubstituierte Cyclopropane (10, 12) gaben keine hydrogenolytische Ringspaltung.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19841170522

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