ISSN:
1436-5073
Schlagwort(e):
FTIR spectroscopy
;
molten salts
;
chloroaluminates
;
structure
;
anion perturbation
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract FTIR reflection spectra of molten chloroaluminates containing alkali earth chlorides showC 2v andC 3v perturbations of AlCl 4 − . The splitting ofv 3(F 2) is proportional to the ionic potential of the counterion. The observation of anion-cation stretching vibrations allows the strength of the interaction to be evaluated. Molten NaAl2OCl5 is assumed to contain the Al4O2C1 10 2− ion.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01349793
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