ISSN:
0009-2940
Keywords:
Carbene complexes
;
Chromium
;
Cyclophanes
;
Chirality
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Pentacarbonyl(4-[2.2]metacyclophanyl(methoxy)carbene)-chromium(0) (6) was prepared according to the Fischer route from 4-bromo[2.2]metacyclophane. Aminolysis with non-chiral and chiral amines affords aminocarbene complexes 7-12. X-Ray structure analyses for 6 and its aminocarbene analogs 7 and 8 indicate that the incorporation of the chromium-carbene fragment has no significant influence on the deformation of the [2.2]metacyclophane skeleton.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300812
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